(1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

Base Information

Chemical Name:(1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one
CAS No.:416843-13-5
Molecular Formula:C₄₅H₇₈O₇S
Molecular Weight:763.176
Hs Code.:

(1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

Synonyms:(1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

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Chemical Property of (1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

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Technology Process of (1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

There total 7 articles about (1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 416843-12-4
(1'''S,2''R,3RS,5S,5''S,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridec-7'-en-9'-ynyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

: 416843-13-5
(1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

Guidance literature:: With sodium acetate; toluene-4-sulfonic acid hydrazide; In monoethylene glycol diethyl ether; at 120 ℃; for 4h;
DOI:10.1016/j.tet.2004.09.011

Reference yield:

: (2R,5S,1'R,1''S)-2-(1'-methoxymethoxy-4'-pentynyl)-5-(1''-hydroxytridecyl)tetrahydrofuran

: 416843-13-5
(1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: 94 percent / (i-Pr)2NEt / CH₂Cl₂ / 24 h / 20 °C

2.1: Et₃N / Cl₂Pd(PPh₃)2 / tetrahydrofuran / 1 °C

2.2: 74 percent / CuI / tetrahydrofuran / 8 h

3.1: 68 percent / H₂ / ClRh(PPh₃)3 / benzene; ethanol / 24 h

With hydrogen; triethylamine; N-ethyl-N,N-diisopropylamine; bis-triphenylphosphine-palladium(II) chloride; Wilkinson's catalyst; In tetrahydrofuran; ethanol; dichloromethane; benzene; 2.1: Sonogashira cross coupling reaction;
DOI:10.1021/ol0102803

Reference yield:

: (E,Z,3RS,5S)-3-(8'-iodooct-7'-enyl)-5-methyl-3-(phenylsulfanyl)tetrahydrofuran-2-one

: 416843-13-5
(1'''S,2''R,3RS,5S,5''S,7'E,13'R)-3-{13'-methoxymethoxy-13-[5''-(1'''-methoxymethoxytridecyl)tetrahydrofuran-2''-yl]tridecyl}-5-methyl-3-(phenylsulphanyl)tetrahydrofuran-2-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: Et₃N / Cl₂Pd(PPh₃)2 / tetrahydrofuran / 1 °C

1.2: 74 percent / CuI / tetrahydrofuran / 8 h

2.1: 68 percent / H₂ / ClRh(PPh₃)3 / benzene; ethanol / 24 h

With hydrogen; triethylamine; bis-triphenylphosphine-palladium(II) chloride; Wilkinson's catalyst; In tetrahydrofuran; ethanol; benzene; 1.1: Sonogashira cross coupling reaction;
DOI:10.1021/ol0102803