C₃₂H₄₇IO₄Si

Base Information

• Chemical Name: C₃₂H₄₇IO₄Si
• CAS No.: 1362110-25-5
• Molecular Formula: C₃₂H₄₇IO₄Si
• Molecular Weight: 650.713
• Mol file: 1362110-25-5.mol

Synonyms:C₃₂H₄₇IO₄Si

Chemical Property of C₃₂H₄₇IO₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₄₇IO₄Si

There total 1 articles about C₃₂H₄₇IO₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C32H48O5Si → C32H47IO4Si (1362110-25-5)

Guidance literature:

With 1H-imidazole; iodine; triphenylphosphine; In tetrahydrofuran; at 0 - 20 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1021/ol300390k

Reference yield:

C32H47IO4Si (1362110-25-5) → C32H48O4Si

Guidance literature:

C₃₂H₄₇IO₄Si; With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 0.166667h; Inert atmosphere;

In tetrahydrofuran; ethyl acetate;

DOI:10.1021/ol300390k

Reference yield:

C32H47IO4Si (1362110-25-5) → C27H36O7 (1362110-62-0)

Guidance literature:

Multi-step reaction with 14 steps

1.1: tert.-butyl lithium / tetrahydrofuran / 0.17 h / -78 °C / Inert atmosphere

1.2: brine

2.1: Burgess Reagent / tetrahydrofuran / 20 - 50 °C / Inert atmosphere

3.1: dichloromethane / 0.33 h / 0 °C / Inert atmosphere

4.1: sodium hydroxide / methanol; water / 0.33 h / 20 °C

5.1: N-chloro-succinimide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrabutyl-ammonium chloride; sodium hydrogencarbonate; potassium carbonate / dichloromethane / 20 °C / Inert atmosphere

6.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran; N,N-dimethyl-formamide / 0.17 h / 0 °C / Inert atmosphere

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 20 °C / Inert atmosphere

7.2: brine

8.1: tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium / dichloromethane / 2 h / 20 °C / Inert atmosphere; Molecular sieve

9.1: 1H-imidazole; iodine; triphenylphosphine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

10.1: sodium cyanoborohydride / tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 66 °C / Inert atmosphere

11.1: ammonia / methanol; water / 6 h / 66 °C

11.2: 0 °C / pH 2

12.1: pyridine / acetonitrile / 0.5 h / 0 °C / Inert atmosphere

13.1: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / toluene / 2 h / 100 °C / Inert atmosphere

14.1: N-ethyl-N,N-diisopropylamine; sodium iodide / 1,2-dimethoxyethane / 24 h / Reflux

With pyridine; 1H-imidazole; tert.-butylhydroperoxide; N-chloro-succinimide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; bis(acetylacetonate)oxovanadium; Burgess Reagent; 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; tetrabutyl-ammonium chloride; ammonia; iodine; tert.-butyl lithium; tri-n-butyl-tin hydride; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium cyanoborohydride; sodium hydrogencarbonate; potassium carbonate; N-ethyl-N,N-diisopropylamine; triphenylphosphine; sodium iodide; sodium hydroxide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; 1,2-dimethoxyethane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 1.1: Barbier type cyclization / 8.1: Sharpless epoxidation;

DOI:10.1021/ol300390k

Downstream raw materials:

C₃₂H₄₆O₃Si

C₃₂H₄₆O₅Si

C₃₄H₅₀O₆Si

C₂₅H₃₀O₆

Refernces