trans-[RuCl₂(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)]

Base Information

• Chemical Name: trans-[RuCl₂(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)]
• CAS No.: 880643-54-9
• Molecular Formula: C₃₄H₃₆Cl₂N₂P₂Ru
• Molecular Weight: 706.597
• Mol file: 880643-54-9.mol

Synonyms:trans-[RuCl₂(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)]

Chemical Property of trans-[RuCl₂(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[RuCl₂(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)]

There total 3 articles about trans-[RuCl₂(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[RuCl2(1,4-bis(diphenylphosphino)butane)]2(μ-1,4-bis(diphenylphosphino)butane) + 1,2-diamino-benzene (95-54-5) → trans-[RuCl2(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)] (880643-54-9)

Guidance literature:

In toluene; at 30 ℃; for 5h; Temperature; Solvent; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.molstruc.2017.09.044

Reference yield: 86.0%

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3) (88496-72-4) + 1,2-diamino-benzene (95-54-5) → trans-[RuCl2(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)] (880643-54-9)

Guidance literature:

In benzene; slight excess of amine amine was added to a C6H6 soln. of Ru-complex at room temp., under Ar, stirring for 1 h in the absence of light; soln. was concd., Et2O was added, solid was collected, washed with hot hexane, Et2O and dried in vac., elem. anal.;

DOI:10.1016/j.inoche.2005.09.032

Reference yield:

mer-[(1,4-bis(diphenylphosphino)butane)aquatrichlororuthenium(III)] (243643-58-5) + 1,2-diamino-benzene (95-54-5) → trans-[RuCl2(1,4-bis(diphenylphosphino)butane)(o-phenylenediamine)] (880643-54-9) + trans-RuCl2(1,4-bis(diphenylphosphino)butane)(o-benzoquinonediimine)

Guidance literature:

In methanol; 1 equiv. of amine was added to a MeOH soln. of Ru-complex at room temp.,under Ar, stirring for 6 h in the absence of light; soln. was concd., Et2O was added, solid was collected, washed with hot hexane, Et2O and dried in vac.; slow evapn. of the freshly prepd. soln. led only to crystn. of the imine-complex, elem. anal.;

DOI:10.1016/j.inoche.2005.09.032

upstream raw materials:

RuCl2(1,4-bis(diphenylphosphino)butane)(PPh3)

1,2-diamino-benzene

mer-[(1,4-bis(diphenylphosphino)butane)aquatrichlororuthenium(III)]