[(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane

Base Information

Chemical Name:[(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane
CAS No.:287411-54-5
Molecular Formula:C₂₇H₃₇BrO₂Si₃
Molecular Weight:557.75
Hs Code.:

Synonyms:[(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane

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Chemical Property of [(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane

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Technology Process of [(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane

There total 3 articles about [(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 3-[diphenyl(trimethylsilyl)silyloxy]-butan-1-ol

: 130350-97-9
(o-bromophenyl)dimethylsilyl chloride

: 287411-54-5
[(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane

Guidance literature:: With dmap; triethylamine; In tetrahydrofuran; at 20 ℃; for 12h;
DOI:10.1021/jo000041d

Reference yield:

: 287411-77-2
methyl 3-[diphenyl(trimethylsilyl)silyloxy]-butyrate

: 287411-54-5
[(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: DIBALH / tetrahydrofuran; hexane / 2 h / -30 - 20 °C

2: 48 percent / Et₃N; DMAP / tetrahydrofuran / 12 h / 20 °C

With dmap; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; hexane; 1: Reduction / 2: Substitution;
DOI:10.1021/jo000041d

Reference yield:

: 61211-96-9
1-chloro-1,1-diphenyl-2,2,2-trimethyldisilane

: 287411-54-5
[(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / Et₃N; DMAP / tetrahydrofuran / 12 h / 20 °C

2: DIBALH / tetrahydrofuran; hexane / 2 h / -30 - 20 °C

3: 48 percent / Et₃N; DMAP / tetrahydrofuran / 12 h / 20 °C

With dmap; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; hexane; 1: Substitution / 2: Reduction / 3: Substitution;
DOI:10.1021/jo000041d