3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose

Base Information

Chemical Name:3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose
CAS No.:875654-82-3
Molecular Formula:C₃₁H₄₆O₄Si₂
Molecular Weight:538.875
Hs Code.:

Synonyms:3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose

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Chemical Property of 3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose

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Technology Process of 3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose

There total 3 articles about 3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₁H₄₆O₅Si₂

: 875654-82-3
3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose

: 3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-α-1-(3-trans-stilbene)-D-ribofuranose

Guidance literature:: With triethylsilane; boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; for 6h;
DOI:10.1039/b513694f

Reference yield:

: 14064-45-0
(E)-3-bromostilbene

: 875654-82-3
3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: tetrahydrofuran; hexane / 1 h / -78 °C

2.1: Et₃SiH; BF₃*OEt₂ / CH₂Cl₂ / 6 h / -78 °C

With triethylsilane; n-butyllithium; boron trifluoride diethyl etherate; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/b513694f

Reference yield:

: 169526-37-8
(6aR,9aS)-2,2,4,4-tetraisopropyltetrahydro-8H-furo[3,2-f ][1,3,5,2,4]trioxadisilocin-8-one

: 875654-82-3
3,5-O-((1,1,3,3-tetraisopropyl)disiloxanediyl)-1,2-dideoxy-β-1-(3-trans-stilbene)-D-ribofuranose

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: tetrahydrofuran; hexane / 1 h / -78 °C

2.1: Et₃SiH; BF₃*OEt₂ / CH₂Cl₂ / 6 h / -78 °C

With triethylsilane; n-butyllithium; boron trifluoride diethyl etherate; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/b513694f