bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate

Base Information

• Chemical Name: bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate
• CAS No.: 1003854-93-0
• Molecular Formula: C₁₀H₁₆Cl₂NO₅P
• Molecular Weight: 332.12
• Mol file: 1003854-93-0.mol

Synonyms:bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate

Chemical Property of bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate

There total 1 articles about bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

3-Sulfolene (77-79-2) + bis(2-chloroethyl)-β-nitroethenylphosphonate (114246-14-9) → bis(2-chloroethyl) (2-nitrophenyl)phosphonate + bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate (1003854-93-0) + bis(2-chloroethyl) (2-nitrocyclohexa-2,4-dien-1-yl)phosphonate + bis(2-chloroethyl) (2-nitrocyclohexa-1,4-dien-1-yl)phosphonate

Guidance literature:

In para-xylene; for 34h; Further byproducts.; Heating;

DOI:10.1134/S1070363207010045

Reference yield: 98.0%

bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate (1003854-93-0) → bis(2-chloroethyl) 2-aminocyclohexyl-1-phosphonate hydrochloride

Guidance literature:

With hydrogen; acidic palladium on charcoal catalyst; In methanol;

DOI:10.1134/S107036320612019X

Reference yield:

bis(2-chloroethyl) (6-nitrocyclohex-3-en-1-yl)phosphonate (1003854-93-0) → dilithium 2-aminocyclohexyl-1-phosphonate

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / H₂ / acidic palladium on charcoal catalyst / methanol

2: 92 percent / aq. LiOH / 24 h / Heating

With lithium hydroxide; hydrogen; acidic palladium on charcoal catalyst; In methanol;

DOI:10.1134/S107036320612019X

upstream raw materials:

3-Sulfolene

bis(2-chloroethyl)-β-nitroethenylphosphonate