dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate

Base Information

• Chemical Name: dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate
• CAS No.: 1013632-32-0
• Molecular Formula: C₂₁H₂₇NO₆S₂
• Molecular Weight: 453.58
• Mol file: 1013632-32-0.mol

Synonyms:dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate

Chemical Property of dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate

There total 1 articles about dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

methyl hydroxy(phenyl)carbamodithioate (1013632-21-7) + 4,4-bis(methoxycarbonyl)-7-methyloct-6-enoic acid (1013632-45-5) → dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate (1013632-32-0)

Guidance literature:

4,4-bis(methoxycarbonyl)-7-methyloct-6-enoic acid; With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 ℃;

methyl hydroxy(phenyl)carbamodithioate; In dichloromethane; at 0 - 20 ℃; Darkness;

DOI:10.1021/ol702832x

Reference yield: 80.0%

dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate (1013632-32-0) → dimethyl 3-(2-(methylthio(phenylimino)methylthio)propan-2-yl)cyclopentane-1,1-dicarboxylate (1013632-33-1)

Guidance literature:

In dichloromethane; at 5 ℃; for 2h; Sunlight irradiation;

DOI:10.1021/ol702832x

Reference yield: 41.0%

dimethyl 2-(3-methylbut-2-enyl)-2-(3-[(methylthiocarbonothioyl)(phenyl)aminooxy]-3-oxopropyl)propanedioate (1013632-32-0) → dimethyl 3-(2-azidopropan-2-yl)cyclopentane-1,1-dicarboxylate (1013632-34-2) + dimethyl 3-(2-(methylthio(phenylimino)methylthio)propan-2-yl)cyclopentane-1,1-dicarboxylate (1013632-33-1)

Guidance literature:

With phenylsulfonyl azide; 2,2'-azobis(isobutyronitrile); In dichloromethane; for 4h; Reflux;

DOI:10.1021/ol702832x

upstream raw materials:

methyl hydroxy(phenyl)carbamodithioate

4,4-bis(methoxycarbonyl)-7-methyloct-6-enoic acid

Downstream raw materials:

dimethyl 3-(2-(methylthio(phenylimino)methylthio)propan-2-yl)cyclopentane-1,1-dicarboxylate

dimethyl 3-(2-azidopropan-2-yl)cyclopentane-1,1-dicarboxylate