(R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol

Base Information

Chemical Name:(R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol
CAS No.:198541-53-6
Molecular Formula:C₄₃H₆₈O₅Si
Molecular Weight:693.095
Hs Code.:

Synonyms:(R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol

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Chemical Property of (R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol

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Technology Process of (R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol

There total 4 articles about (R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 198541-52-5
(6E,10E,14E)-(R)-1-(tert-Butyl-diphenyl-silanyloxy)-heptacosa-6,10,14-trien-3-ol

: 198541-53-6
(R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol

Guidance literature:: With (F₃CCO₂)ReO₃; trifluoroacetic anhydride; In dichloromethane; for 8h;
DOI:10.1021/ja981324e

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 198541-53-6
(R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / diisopropylethylamine / CH₂Cl₂ / 16 h / Ambient temperature

2: 48 percent / Re₂O₇, trifluoroacetic anhydride / tetrahydrofuran / 6 h / 0 - 20 °C

With rhenium(VII) oxide; N-ethyl-N,N-diisopropylamine; trifluoroacetic anhydride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja964273z

Reference yield:

: 198541-51-4
(6E,10E,14E)-(R)-Heptacosa-6,10,14-triene-1,3-diol

: 198541-53-6
(R)-1-{(2S,5R,2'S,5'R,2''R,5''R)-5''-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-dodecahydro-[2,2';5',2'']terfuran-5-yl}-tridecan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / diisopropylethylamine / CH₂Cl₂ / 16 h / Ambient temperature

2: 48 percent / Re₂O₇, trifluoroacetic anhydride / tetrahydrofuran / 6 h / 0 - 20 °C

With rhenium(VII) oxide; N-ethyl-N,N-diisopropylamine; trifluoroacetic anhydride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja964273z