(+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate

Base Information

Chemical Name:(+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate
CAS No.:398460-20-3
Molecular Formula:C₁₄H₁₆O₅
Molecular Weight:264.278
Hs Code.:

Synonyms:(+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate

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Technology Process of (+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate

There total 3 articles about (+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 398460-16-7
(+)-(1S,4S,5S)-methyl 4-O-acetyl-1-O-benzyl-2,3-dideoxyhex-2-enopyranuronate

: 398460-20-3
(+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate

Guidance literature:: With potassium carbonate; In methanol; for 3.5h;
DOI:10.1021/ol017026v

Reference yield:

: 57690-62-7
methyl 3,4-di-O-acetyl-1,2-dideoxy-D-arabino-hex-1-enopyranuronate

: 398460-20-3
(+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate

Guidance literature:: Multi-step reaction with 2 steps

1: 53 percent / BF₃*OEt₂ / CH₂Cl₂ / 96 h / -10 °C

2: 96 percent / K₂CO₃ / methanol / 3.5 h

With boron trifluoride diethyl etherate; potassium carbonate; In methanol; dichloromethane; 1: Ferrier reaction;
DOI:10.1021/ol017026v

Reference yield:

: 100-51-6,185532-71-2
benzyl alcohol

: 398460-20-3
(+)-(1S,4S,5S)-methyl 1-O-benzyl-4-hydroxy-2,3-dideoxyhex-2-enopyranuronate

Guidance literature:: Multi-step reaction with 2 steps

1: 53 percent / BF₃*OEt₂ / CH₂Cl₂ / 96 h / -10 °C

2: 96 percent / K₂CO₃ / methanol / 3.5 h

With boron trifluoride diethyl etherate; potassium carbonate; In methanol; dichloromethane; 1: Ferrier reaction;
DOI:10.1021/ol017026v