RhCOBr((C₆H₅)4CH₂AsP)2PtBr₂

Base Information

• Chemical Name: RhCOBr((C₆H₅)4CH₂AsP)2PtBr₂
• CAS No.: 97112-56-6
• Molecular Formula: C₅₁H₄₄As₂Br₃OP₂PtRh
• Molecular Weight: 1422.4
• Mol file: 97112-56-6.mol

Synonyms:RhCOBr((C₆H₅)4CH₂AsP)2PtBr₂

Chemical Property of RhCOBr((C₆H₅)4CH₂AsP)2PtBr₂

Chemical Property:

Purity/Quality:

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Technology Process of RhCOBr((C₆H₅)4CH₂AsP)2PtBr₂

There total 1 articles about RhCOBr((C₆H₅)4CH₂AsP)2PtBr₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

{cis-Cl2(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl} (88867-59-8,88928-90-9) → RhCOBr((C6H5)4CH2AsP)2PtBr2 (97112-56-6)

Guidance literature:

With NaBr; In dichloromethane; water; acetone; a soln. of NaBr in H2O-acetone was added to a soln. of complex in CH2Cl2; the mixt. was stirred for 30 min; evapd., filtered, washed with H2O and MeOH, recrystd. from CH2Cl2/MeOH and CH2Cl2/Et2O; elem. anal.;

DOI:10.1021/om00127a024

Reference yield: 38.0%

RhCOBr((C6H5)4CH2AsP)2PtBr2 (97112-56-6) → RhCOCl((C6H5)4CH2AsP)2PtCl2 (97112-55-5)

Guidance literature:

With NaCl; In methanol; dichloromethane; water; an excess of NaCl in H2O-MeOH was added to a soln. of complex in CH2Cl2, the mixt. was stirred for 2 h; evapd., filtered, washed with H2O and MeOH, recrystd. from CH2Cl2/Et2O and vac.-dried;

DOI:10.1021/om00127a024

upstream raw materials:

{cis-Cl₂(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl}

Downstream raw materials:

RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂