2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate

Base Information

• Chemical Name: 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate
• CAS No.: 100422-07-9
• Molecular Formula: CF₃O₃S*C₈H₇F₃I
• Molecular Weight: 436.114
• Mol file: 100422-07-9.mol

Synonyms:2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate

Chemical Property of 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate

There total 3 articles about 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

trimethylphenylsilane (768-32-1) + 1-iodo>-1H,1H-perfluoroethane (166903-48-6) → 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate (100422-07-9)

Guidance literature:

In dichloromethane; for 2h; -30 deg C to 0 deg C;

DOI:10.1016/0040-4039(95)00275-H

Reference yield: 76.0%

→ 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate (100422-07-9)

Guidance literature:

Reference yield: 68.0%

trifluorormethanesulfonic acid (1493-13-6) + (2,2,2-trifluoroethyl)-λ3-iodanediyl bis(2,2,2-trifluoroacetate) (100422-04-6) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate (100422-07-9)

Guidance literature:

In dichloromethane; at 0 ℃; for 24h;

DOI:10.1039/c5cc00519a

upstream raw materials:

trimethylphenylsilane

1-iodo>-1H,1H-perfluoroethane

trifluorormethanesulfonic acid

(2,2,2-trifluoroethyl)-λ³-iodanediyl bis(2,2,2-trifluoroacetate)

Downstream raw materials:

(2,2,2-trifluoroethyl)benzene

[1,1';4',1'']terphenyl

o-terphenyl

3,5-dichlorobiphenyl

Refernces

• 1、 Tolnai, Gergely L.,Székely, Anna,Makó, Zita,Gáti, Tamás,Daru, János,Bihari, Tamás,Stirling, András,Novák, Zoltán. "Efficient direct 2,2,2-trifluoroethylation of indoles via C-H functionalization". . p. 4488 - 4491. Retrieved 2015.