(r,s)-Josiphos

Base Information

• Chemical Name: (r,s)-Josiphos
• CAS No.: 155806-35-2
• Molecular Formula: C36H44FeP2
• Molecular Weight: 594.53
• Hs Code.: 29319090
• DSSTox Substance ID: DTXSID70450694
• Mol file: 155806-35-2.mol

Synonyms:(r,s)-josiphos;(R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine, 97+%;(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine;DTXSID70450694;MFCD00800284;AKOS037503807;SC11457;BP-12231;(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine Ethanol Adduct;(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine, >=97%

Chemical Property of (r,s)-Josiphos

Chemical Property:

• Appearance/Colour: orange crystalline powder
• Melting Point: ~95 ºC
• PSA: 27.18000
• LogP: 9.12070
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 594.226761
• Heavy Atom Count: 39
• Complexity: 644

Purity/Quality:

98%,99%, ^*data from raw suppliers

(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct, min. 97% (R)-(S)-JOSIPHOS ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC([C]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3)P(C4CCCCC4)C5CCCCC5.C1=C[CH]C=C1.[Fe]
• Isomeric SMILES: C[C@H]([C]1C=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3)P(C4CCCCC4)C5CCCCC5.C1=C[CH]C=C1.[Fe]
• Uses: It may be used in the preparation of cyclopentadienyliridium complexes, [IrCl(PP)]2 and [IrCp(PP)]. (Cp= cyclopentadienyl; PP= (R)-1-[(SP)-2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine)