(1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene

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Chemical Name:(1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene
CAS No.:126798-15-0
Molecular Formula:C₂₇H₂₉NO₃
Molecular Weight:415.532
Hs Code.:

Synonyms:(1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene

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Chemical Property of (1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene

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Technology Process of (1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene

There total 9 articles about (1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: (1α,4α,5β)-1,4-bis(benzyloxy)-3-<(benzyloxy)methyl>-5-azido-2-cyclopentene

: 126798-15-0
(1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene

Guidance literature:: With hydrogen; Lindlar catalyst; In methanol; for 1h; Ambient temperature;
DOI:10.1016/S0040-4039(01)80539-6

Reference yield:

: (1α,4α,5β)-1-(benzyloxy)-3-<(benzyloxy)methyl>-4-(acetyloxy)-5-azido-2-cyclopentene

: 126798-15-0
(1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / NaOMe, MeOH / 0.5 h / Ambient temperature

2: 1) NaH / 1) DMF, oil, 30 min, 2) 30 min

3: 86 percent / H₂ / Lindlar-catalyst / methanol / 760 Torr

With methanol; hydrogen; sodium methylate; sodium hydride; Lindlar's catalyst; In methanol;
DOI:10.1021/jo00033a031

Reference yield:

: 126798-09-2
Acetic acid (1S,4R,5R)-4-benzyloxy-2-benzyloxymethyl-5-methanesulfonyloxy-cyclopent-2-enyl ester

: 126798-15-0
(1β,2α,5α)-1-amino-2,5-bis(benzyloxy)-3-<(benzyloxy)methyl>-3-cyclopentene

Guidance literature:: Multi-step reaction with 4 steps

1: 43 percent / LiN₃ / dimethylsulfoxide / 48 h / 110 °C

2: 98 percent / NaOMe, MeOH / 0.5 h / Ambient temperature

3: 1) NaH / 1) DMF, oil, 30 min, 2) 30 min

4: 86 percent / H₂ / Lindlar-catalyst / methanol / 760 Torr

With methanol; lithium azide; hydrogen; sodium methylate; sodium hydride; Lindlar's catalyst; In methanol; dimethyl sulfoxide;
DOI:10.1021/jo00033a031