(1,2-METHANOFULLERENE C60)-61,61-DICARBOXYLIC ACID DIETHYL ESTER

Base Information

• Chemical Name: (1,2-METHANOFULLERENE C60)-61,61-DICARBOXYLIC ACID DIETHYL ESTER
• CAS No.: 155679-98-4
• Molecular Formula: C67H10 O4
• Molecular Weight: 878.814
• Mol file: 155679-98-4.mol

Synonyms:3'H-Cyclopropa[1,2][5,6]fullerene-C60-Ih-3',3'-dicarboxylicacid, diethyl ester (9CI)

Chemical Property of (1,2-METHANOFULLERENE C60)-61,61-DICARBOXYLIC ACID DIETHYL ESTER

Chemical Property:

• PSA: 52.60000
• Density: 2.72±0.1 g/cm3(Predicted)
• LogP: 7.24660
• Storage Temp.: 2-8°C

Purity/Quality:

C60 DERIVATIVES 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1,2-METHANOFULLERENE C60)-61,61-DICARBOXYLIC ACID DIETHYL ESTER

There total 1 articles about (1,2-METHANOFULLERENE C60)-61,61-DICARBOXYLIC ACID DIETHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

Diethyl 2-bromomalonate (685-87-0) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) → diethyl 3'H-cyclopropa[1,5](C60-Ih)[5,6]fullerene-dicarboxylate (155679-98-4)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In 1,2-dichloro-benzene; at 20 ℃; for 1h;

DOI:10.1002/chem.202005046

upstream raw materials:

Diethyl 2-bromomalonate

fullerene-C₆₀