(1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

Base Information

Chemical Name:(1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol
CAS No.:1360459-96-6
Molecular Formula:C₁₇H₂₃NO₂
Molecular Weight:273.375
Hs Code.:

Synonyms:(1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

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Chemical Property of (1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

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Technology Process of (1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

There total 4 articles about (1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 41719-73-7
(2S)-3-exo-aminoisoborneol

: 90-02-8
salicylaldehyde

: 1360459-96-6
(1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

Guidance literature:: With magnesium sulfate; toluene-4-sulfonic acid; In toluene; for 24h; Inert atmosphere; Reflux;
DOI:10.1016/j.tetasy.2014.03.001

Reference yield:

: 663-17-2
camphorquinone monooxime

: 1360459-96-6
(1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: water / 16 h / Reflux

2.1: lithium aluminium tetrahydride / 24.8 h / 0 °C / Reflux

2.2: 20 °C

3.1: toluene-4-sulfonic acid; magnesium sulfate / toluene / 24 h / Inert atmosphere; Reflux

With lithium aluminium tetrahydride; water; magnesium sulfate; toluene-4-sulfonic acid; In toluene;
DOI:10.1016/j.tetasy.2014.03.001

Reference yield:

: 13854-87-0
E-3-isonitrosocamphor

: 1360459-96-6
(1R,2S,3R,4S)-3-((E)-(2-hydroxybenzylidene)amino)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium aluminium tetrahydride / 24.8 h / 0 °C / Reflux

1.2: 20 °C

2.1: toluene-4-sulfonic acid; magnesium sulfate / toluene / 24 h / Inert atmosphere; Reflux

With lithium aluminium tetrahydride; magnesium sulfate; toluene-4-sulfonic acid; In toluene;
DOI:10.1016/j.tetasy.2014.03.001