methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside

Base Information

• Chemical Name: methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside
• CAS No.: 125084-96-0
• Molecular Formula: C₂₈H₃₉NO₁₃
• Molecular Weight: 597.617
• Mol file: 125084-96-0.mol

Synonyms:methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside

Chemical Property of methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside

There total 12 articles about methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

3,4,6-tri-O-acetyl-2-deoxy-2-formamido-α-D-glucopyranosyl trichloroacetimidate (125084-88-0) + methyl 2-O-benzyl-6-deoxy-4-O-methyl-β-D-galactopyranoside (125084-89-1) → methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside (125084-96-0)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; Ambient temperature;

DOI:10.1016/0008-6215(89)85044-X

Reference yield: 34.0%

3,4,6-tri-O-acetyl-2-deoxy-2-formamido-α-D-glucopyranosyl chloride (125084-87-9) + methyl 2-O-benzyl-6-deoxy-4-O-methyl-β-D-galactopyranoside (125084-89-1) → methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside (125084-96-0)

Guidance literature:

With tin(II) trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; Ambient temperature;

DOI:10.1016/0008-6215(89)85044-X

Reference yield: 29.0%

1,3,4,6-Tetra-O-acetyl-2-desoxy-2-formamido-β-D-glucose (76695-53-9) + methyl 2-O-benzyl-6-deoxy-4-O-methyl-β-D-galactopyranoside (125084-89-1) → methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-formamido-β-D-glucopyranosyl)-β-D-galactopyranoside (125084-96-0)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; 4 Angstroem MS; In dichloromethane; Ambient temperature;

DOI:10.1016/S0040-4039(01)80443-3

upstream raw materials:

1,3,4,6-Tetra-O-acetyl-2-desoxy-2-formamido-β-D-glucose

methyl 2-O-benzyl-6-deoxy-4-O-methyl-β-D-galactopyranoside

methyl 2-O-benzyl-6-deoxy-4-O-methyl-β-D-galactopyranoside

(4-nitrophenyl) formate

Downstream raw materials:

methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-β-D-arabino-hexapyranosyl)-β-D-galactopyranoside

methyl 2-O-benzyl-6-deoxy-4-O-methyl-3-O-(3,4,6-tri-O-acetyl-2-deoxy-2-isocyano-β-D-glucopyranosyl)-β-D-galactopyranoside