7,12-diphenylbenzo[k]fluoranthene

Base Information

• Chemical Name: 7,12-diphenylbenzo[k]fluoranthene
• CAS No.: 16391-62-1
• Molecular Formula: C₃₂H₂₀
• Molecular Weight: 404.511
• Mol file: 16391-62-1.mol

Synonyms:(7,12-diphenyl)benzofluoranthene

Chemical Property of 7,12-diphenylbenzo[k]fluoranthene

Chemical Property:

• Melting Point: 250 °C
• Boiling Point: 613.8±35.0 °C(Predicted)
• Density: 1.238±0.06 g/cm3(Predicted)

Purity/Quality:

98% ^*data from raw suppliers

7,12-Diphenylbenzo[k]fluoranthene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7,12-diphenylbenzo[k]fluoranthene

There total 21 articles about 7,12-diphenylbenzo[k]fluoranthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

acecyclone (641-57-6) + anthranilic acid (118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4) → (7,12-diphenyl)benzofluoranthene (16391-62-1)

Guidance literature:

With isopentyl nitrite; In 1,2-dichloro-ethane; for 1.5h; Heating;

Reference yield: 96.0%

C32H20O → (7,12-diphenyl)benzofluoranthene (16391-62-1)

Guidance literature:

With hydrogen bromide; acetic acid; In water; for 3h; Reflux;

Reference yield: 92.26%

10.13-Diphenyl-10.13-endoxy-11:12-benzo-9.10.13.14-tetrahydrofluoranthen (13093-44-2,36213-63-5,36213-64-6) → (7,12-diphenyl)benzofluoranthene (16391-62-1)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; for 4h; Reflux;

upstream raw materials:

1,3-diphenylisobenzofuran

acenaphthylene

7,12-diphenyl-(6br,12ac)-6b,7,12,12a-tetrahydro-7ξ,12ξ-epoxido-benzo[k]fluoranthene

1,2-dibromoacenaphthylene

Downstream raw materials:

7,12-diphenylbenzo[k]fluoranthen-3-ylboronic acid

C₄₂H₂₅Br

2-(7,12-diphenylbenzo[k]fluoranthen-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

3-bromo-7,12-diphenylbenzo[k]fluoranthene

Refernces

• 1、 Xu, Shengjie,Chen, Kejuan,Chen, Hui,Yao, Jiannian,Zhu, Xiaozhang. "Stereocontrolled Synthesis of Benzo[k]fluoranthenes - An Unexpected Isomerization Mediated by Rhodacyclopentadiene". . p. 16442 - 16447. Retrieved 2014.
• 2、 Takahashi, Hiroto,Honjo, Yusaku,Shibata, Yu,Nagashima, Yuki,Tanaka, Ken. "Dienylation of Unfunctionalized Arenes with 1,6-Diynes via Rhodium-Catalyzed Directing-Group-Free C-H Bond Activation". . p. 3065 - 3074. Retrieved 2021/01/21.
• 3、 -. "7,12-diphenylbenzo[k]fluoranthene derivatives with electron donor-receptor structures and preparation method and application thereof". . . Retrieved 2018/03/24.