3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

Base Information

Chemical Name:3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole
CAS No.:156454-59-0
Molecular Formula:C₂₁H₂₆N₂O₂
Molecular Weight:338.45
Hs Code.:

Synonyms:3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

Suppliers and Price of 3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

There total 6 articles about 3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 156454-58-9
5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethyl-3-(2'-nitrophenyl)pyrrole

: 156454-59-0
3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

Guidance literature:: With hydrazine hydrate; Raney Nickel R; In ethanol; at 60 ℃; for 1.5h;

Reference yield:

: 129045-01-8
1,4-dimethyl-3-(2'-nitrophenyl)pyrrole-2-carbaldehyde

: 156454-59-0
3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / NaH / 1,2-dimethoxy-ethane / 6 h / Ambient temperature

2: 64 percent / 36percent HCl / tetrahydrofuran / 7 h / 0 °C

3: 85 percent / 3 eq DIBAL-H / CH₂Cl₂ / 2 h / -70 °C

4: 67 percent / MnO₂ / CCl₄ / 1.5 h / Ambient temperature

5: 75 percent / pyridinium tosylate / benzene / Heating

6: 93 percent / hydrazine hydrate / aq. Raney Nickel R 50percent / ethanol / 1.5 h / 60 °C

With hydrogenchloride; manganese(IV) oxide; pyridinium p-toluenesulfonate; sodium hydride; diisobutylaluminium hydride; hydrazine hydrate; Raney Nickel R; In tetrahydrofuran; tetrachloromethane; 1,2-dimethoxyethane; ethanol; dichloromethane; benzene;

Reference yield:

: 156454-57-8
5-(but-1-enyl)-1,4-dimethyl-3-(2'-nitrophenyl)-2-(2-formylvinyl)pyrrole

: 156454-59-0
3-(2'aminophenyl)-5-(but-1-enyl)-2-<2-(1,3-dioxolan-2-yl)vinyl>-1,4-dimethylpyrrole

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / pyridinium tosylate / benzene / Heating

2: 93 percent / hydrazine hydrate / aq. Raney Nickel R 50percent / ethanol / 1.5 h / 60 °C

With pyridinium p-toluenesulfonate; hydrazine hydrate; Raney Nickel R; In ethanol; benzene;