benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

Base Information

Chemical Name:benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate
CAS No.:171365-83-6
Molecular Formula:C₃₇H₄₄O₃Si
Molecular Weight:564.84
Hs Code.:

Synonyms:benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

Suppliers and Price of benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

There total 4 articles about benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 106-41-2
4-bromo-phenol

: 171365-83-6
benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

Guidance literature:: Multi-step reaction with 3 steps

1: 41 percent / conc. H₂SO₄ / CH₂Cl₂ / 96 h / Heating

2: 85 percent / 4-(N,N-dimethylamino)pyridine, Et₃N / dimethylformamide / 4 h / Ambient temperature

3: 1.) Mg, I₂, 2.) ZnCl₂, 3.) NiCl₂*1,2-bis(diphenylphosphino)ethane

With dmap; 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; sulfuric acid; iodine; magnesium; triethylamine; zinc(II) chloride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm00026a006

Reference yield:

: 590-67-0
1-Methylcyclohexanol

: 171365-83-6
benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

Guidance literature:: Multi-step reaction with 3 steps

1: 41 percent / conc. H₂SO₄ / CH₂Cl₂ / 96 h / Heating

2: 85 percent / 4-(N,N-dimethylamino)pyridine, Et₃N / dimethylformamide / 4 h / Ambient temperature

3: 1.) Mg, I₂, 2.) ZnCl₂, 3.) NiCl₂*1,2-bis(diphenylphosphino)ethane

With dmap; 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; sulfuric acid; iodine; magnesium; triethylamine; zinc(II) chloride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm00026a006

Reference yield:

: 111008-55-0
4-bromo-2-(1-methylcyclohexyl)-phenol

: 171365-83-6
benzyl 6-<3-(1-methylcyclohexyl)-4-<(tert-butyldimethylsilyl)oxy>phenyl>-2-naphthoate

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / 4-(N,N-dimethylamino)pyridine, Et₃N / dimethylformamide / 4 h / Ambient temperature

2: 1.) Mg, I₂, 2.) ZnCl₂, 3.) NiCl₂*1,2-bis(diphenylphosphino)ethane

With dmap; 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; iodine; magnesium; triethylamine; zinc(II) chloride; In N,N-dimethyl-formamide;
DOI:10.1021/jm00026a006