Oxiranemethanol, 3-butyl- (9CI)

Base Information

• Chemical Name: Oxiranemethanol, 3-butyl- (9CI)
• CAS No.: 154802-30-9
• Molecular Formula: C7H14 O2
• Molecular Weight: 130.187
• Mol file: 154802-30-9.mol

Synonyms:Oxiranemethanol,3-butyl- (9CI)

Chemical Property of Oxiranemethanol, 3-butyl- (9CI)

Chemical Property:

• PSA: 32.76000
• LogP: 0.93630

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Oxiranemethanol, 3-butyl- (9CI)

There total 1 articles about Oxiranemethanol, 3-butyl- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-hept-2-en-1-ol (33467-76-4) → (E)-2-Heptenal (18829-55-5) + (±)-2,3-epoxy-1-heptanol (154802-30-9)

Guidance literature:

With dihydrogen peroxide; Sucrose; sodium tungstate; In phosphate buffer; at 2 ℃; for 24h; pH=7; Title compound not separated from byproducts.;

DOI:10.1039/b108352j

Reference yield:

(±)-2,3-epoxy-1-heptanol (154802-30-9) → (4R,5R)-2-(3-Butyl-oxiranylmethoxy)-1,3-dimethyl-4,5-bis-(3-trifluoromethyl-phenyl)-[1,3,2]diazaphospholidine 2-selenide

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) PCl₃, Et₃N / 1.) CDCl₃

2: Se₈ / CDCl₃

With red selenium; triethylamine; phosphorus trichloride; In chloroform-d1;

DOI:10.1021/jo00091a019

Reference yield:

(±)-2,3-epoxy-1-heptanol (154802-30-9) → (4R,5R)-2-(3-Butyl-oxiranylmethoxy)-1,3-dimethyl-4,5-bis-(3-trifluoromethyl-phenyl)-[1,3,2]diazaphospholidine 2-sulfide

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) PCl₃, Et₃N / 1.) CDCl₃

2: S₈ / CDCl₃

With sulfur; triethylamine; phosphorus trichloride; In chloroform-d1;

DOI:10.1021/jo00091a019

upstream raw materials:

(E)-hept-2-en-1-ol

Downstream raw materials:

1,2-heptanediol

(4R)-4-butyl-2-phenyl-1,3-dioxane

3-mercaptoheptyl acetate

Refernces