Nb(I)(N[neopentyl]-3,5-Me₂C₆H₃)3

Base Information

• Chemical Name: Nb(I)(N[neopentyl]-3,5-Me₂C₆H₃)3
• CAS No.: 877119-58-9
• Molecular Formula: C₃₉H₆₀IN₃Nb
• Molecular Weight: 790.736

Synonyms:Nb(I)(N[neopentyl]-3,5-Me₂C₆H₃)3

Chemical Property of Nb(I)(N[neopentyl]-3,5-Me₂C₆H₃)3

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Technology Process of Nb(I)(N[neopentyl]-3,5-Me₂C₆H₃)3

There total 1 articles about Nb(I)(N[neopentyl]-3,5-Me₂C₆H₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

[NbI2(N(neopentyl)(3,5-Me2C6H3))3] (521085-28-9) → Nb(I)(N[neopentyl]-3,5-Me2C6H3)3 (877119-58-9)

Guidance literature:

With Mg(THF)3(anthracene); In tetrahydrofuran; byproducts: MgI2, anthracene; under N2 atm. thawing soln. Nb complex in THF Mg-compound was added, mixt. was warmed to room temp., stirred for 1.5 h; mixt. was evapd. in vac., residue was extd. with pentane, filtered through Celite, filtrate was concd., frozen, soln. was quickly cold-filtered through Celite, filtrate was concd., stored at -35°C for 2 days; elem. anal.;

DOI:10.1021/ja056408j

Reference yield: 54.0%

Na[(N2)Mo(N[t-Bu]3,5-Me2C6H3)3] + Nb(I)(N[neopentyl]-3,5-Me2C6H3)3 (877119-58-9) → (3,5-Me2C6H3)[neopentyl]N)3Nb(μ-N2)Mo(N[t-butyl]-3,5-Me2C6H3)3

Guidance literature:

In tetrahydrofuran; byproducts: NaI; under N2 atm. thawing soln. Nb-complex in THF was added dropwise to thawing soln. Mo-complex in THF, mixt. was warmed to room temp.to stir for 30 min; mixt. was evapd. in vac., residue was extd. with pentane, filtered through Celite, filtrate was evapd., redissolved in Et2O, stored at -35°C for several days; elem. anal.;

DOI:10.1021/ja056408j

Reference yield: 48.0%

Nb(I)(N[neopentyl]-3,5-Me2C6H3)3 (877119-58-9) + Na[(N2)Mo(N[neopentyl]-3,5-Me2C6H3)3] → (3,5-Me2C6H3)[neopentyl]N)3Nb(μ-N2)Mo(N[neopentyl]-3,5-Me2C6H3)3

Guidance literature:

In tetrahydrofuran; byproducts: NaI; under N2 atm. thawing soln. Nb-complex in THF was added dropwise to thawing soln. Mo-complex in THF, mixt. was warmed to room temp.to stir for 30 min; mixt. was evapd. in vac., residue was extd. with pentane, filtered through Celite, filtrate was evapd., redissolved in Et2O, stored at -35°C for several days; elem. anal.;

DOI:10.1021/ja056408j

upstream raw materials:

[NbI₂(N(neopentyl)(3,5-Me₂C₆H₃))3]

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