ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate

Base Information

Chemical Name:ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate
CAS No.:134418-86-3
Molecular Formula:C₁₉H₂₀O₂
Molecular Weight:280.367
Hs Code.:

Synonyms:ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate

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Technology Process of ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate

There total 2 articles about ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 126554-34-5
ethyl (E)-2-diazo-6-phenyl-1-hexa-3,5-dienoate

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 134418-86-3
ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate

Guidance literature:: rhodium(II) acetate; In dichloromethane; for 0.166667h; Heating;
DOI:10.1021/jo00012a011

Reference yield:

: 89861-43-8,105952-21-4
ethyl 6-phenyl-1-hexa-3,5-dienoate

: 134418-86-3
ethyl endo-4-((E)-2-phenylethenyl)bicyclo<3.2.1>octa-2,6-diene-2-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 56 percent / DBU, p-acetamidobenzenesulfonyl azide / acetonitrile / 4 h / 0 °C

2: 72 percent / rhodium(II) acetate / CH₂Cl₂ / 0.17 h / Heating

With 4-acetamidobenzenesulfonyl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene; rhodium(II) acetate; In dichloromethane; acetonitrile;
DOI:10.1021/jo00012a011