2-Cyclopenten-1-ol,4-amino-5-(methylthio)-,[1R-(1alpha,4alpha,5beta)]-(9CI)

Base Information

Chemical Name:2-Cyclopenten-1-ol,4-amino-5-(methylthio)-,[1R-(1alpha,4alpha,5beta)]-(9CI)
CAS No.:154396-79-9
Molecular Formula:C₆H₁₁NOS
Molecular Weight:145.225
Hs Code.:
Mol file:154396-79-9.mol

Synonyms:2-Cyclopenten-1-ol,4-amino-5-(methylthio)-,[1R-(1alpha,4alpha,5beta)]-(9CI)

Suppliers and Price of 2-Cyclopenten-1-ol,4-amino-5-(methylthio)-,[1R-(1alpha,4alpha,5beta)]-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 2-Cyclopenten-1-ol,4-amino-5-(methylthio)-,[1R-(1alpha,4alpha,5beta)]-(9CI)

Chemical Property:

Boiling Point:273.5±40.0 °C(Predicted)
PKA:13.75±0.60(Predicted)
PSA：71.55000
Density:1.21±0.1 g/cm3(Predicted)
LogP:0.67630

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Cyclopenten-1-ol,4-amino-5-(methylthio)-,[1R-(1alpha,4alpha,5beta)]-(9CI)

There total 3 articles about 2-Cyclopenten-1-ol,4-amino-5-(methylthio)-,[1R-(1alpha,4alpha,5beta)]-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 134153-75-6
(1R,2R,5S)-1-(methylthio)-2-hydroxy-5-(N-((R)-hydroxyphenylacetyl)amino)cyclopent-3-ene

: 154396-79-9
(1R,2R,5S)-1-(methylthio)-2-hydroxy-5-aminocyclopent-3-ene

Guidance literature:: With sodium hydroxide; for 23h; Heating;
DOI:10.1021/ja00081a017

Reference yield:

: 124412-11-9
1-(methylthio)cyclopenta-2,4-diene

: 154396-79-9
(1R,2R,5S)-1-(methylthio)-2-hydroxy-5-aminocyclopent-3-ene

Guidance literature:: Multi-step reaction with 3 steps

1: 24 percent / Bu₄NIO₄ / CCl₄; methanol / 1 h / 0 °C

2: 78 percent / Al-Hg, H₂O / tetrahydrofuran / 16 h / 0 - 25 °C

3: 71 percent / 15percent aq. NaOH / 23 h / Heating

With sodium hydroxide; aluminium amalgam; water; tetrabutylammonium periodite; In tetrahydrofuran; methanol; tetrachloromethane;
DOI:10.1021/ja00081a017

Reference yield:

: 134153-71-2
(1R,4S,7R)-3-(2-(R)-hydroxy-2-phenylacetyl)-7-(methylthio)-2-oxa-3-azabicyclo<2.2.1>hept-5-ene

: 154396-79-9
(1R,2R,5S)-1-(methylthio)-2-hydroxy-5-aminocyclopent-3-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / Al-Hg, H₂O / tetrahydrofuran / 16 h / 0 - 25 °C

2: 71 percent / 15percent aq. NaOH / 23 h / Heating

With sodium hydroxide; aluminium amalgam; water; In tetrahydrofuran;
DOI:10.1021/ja00081a017