(2S,2'S,3S,3'S)-Ph-BIBOP

Base Information

• Chemical Name: (2S,2'S,3S,3'S)-Ph-BIBOP
• CAS No.: 1202033-21-3
• Molecular Formula: C₃₄H₃₆O₂P₂
• Molecular Weight: 538.606
• Mol file: 1202033-21-3.mol

Synonyms:(2S,2'S,3S,3'S)-3,3'-di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole

Chemical Property of (2S,2'S,3S,3'S)-Ph-BIBOP

Chemical Property:

• Boiling Point: 681.4±55.0 °C(Predicted)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

97% purity >99% ee ^*data from raw suppliers

(2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2S,2'S,3S,3'S)-Ph-BIBOP 3'S)-Ph-BIBOP ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2S,2'S,3S,3'S)-Ph-BIBOP

There total 2 articles about (2S,2'S,3S,3'S)-Ph-BIBOP which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(2S,2'S,3R,3'R)-3,3'-di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole bisoxide (1202033-13-3) → (2S,2'S,3S,3'S)-3,3'-di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (1202033-21-3,2301856-53-9)

Guidance literature:

With trichlorosilane; triethylamine; In toluene; at 80 ℃; Inert atmosphere;

DOI:10.1021/ol9025815

Reference yield: 84.0%

→ (2S,2'S,3S,3'S)-3,3'-di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (1202033-21-3,2301856-53-9)

Guidance literature:

upstream raw materials:

(2S,2'S,3R,3'R)-3,3'-di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole bisoxide