1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

Base Information

Chemical Name:1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene
CAS No.:863782-51-8
Molecular Formula:C₃₀H₅₂OSi₂
Molecular Weight:484.913
Hs Code.:

1-<i>tert</i>-butyl-3-[1-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

Synonyms:1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

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Chemical Property of 1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

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Technology Process of 1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

There total 3 articles about 1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 863782-50-7
1-bromo-3-tert-butyl-5-[2-[tris(isopropyl)silyl]ethynyl]benzene

: 147455-22-9
1-(tert-butyldimethylsilyloxy)-2-iodoprop-2-ene

: 863782-51-8
1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

Guidance literature:: 1-bromo-3-tert-butyl-5-[2-[tris(isopropyl)silyl]ethynyl]benzene; With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 0.0833333h;

With zinc dibromide; In tetrahydrofuran; at -78 - 0 ℃; for 0.5h;

1-(tert-butyldimethylsilyloxy)-2-iodoprop-2-ene; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 16h;
DOI:10.1002/anie.200500484

Reference yield:

: 89343-06-6
tris-iso-propylsilyl acetylene

: 863782-51-8
1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 99 percent / Pd(PPh₃)2Cl₂; CuI; Et₃N / tetrahydrofuran / 16 h / 20 °C

2.1: t-BuLi / tetrahydrofuran / 0.08 h / -78 °C

2.2: ZnBr₂ / tetrahydrofuran / 0.5 h / -78 - 0 °C

2.3: 99 percent / Pd(Ph₃P)4 / tetrahydrofuran / 16 h / 20 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tert.-butyl lithium; triethylamine; In tetrahydrofuran; 1.1: Sonogashira coupling;
DOI:10.1002/anie.200500484

Reference yield:

: 186772-43-0
1-bromo-3-(tert-butyl)-5-iodobenzene

: 863782-51-8
1-tert-butyl-3-[1-(tert-butyl-dimethyl-silanyloxymethyl)-vinyl]-5-[(triisopropylsilanyl)-ethynyl]-benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 99 percent / Pd(PPh₃)2Cl₂; CuI; Et₃N / tetrahydrofuran / 16 h / 20 °C

2.1: t-BuLi / tetrahydrofuran / 0.08 h / -78 °C

2.2: ZnBr₂ / tetrahydrofuran / 0.5 h / -78 - 0 °C

2.3: 99 percent / Pd(Ph₃P)4 / tetrahydrofuran / 16 h / 20 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tert.-butyl lithium; triethylamine; In tetrahydrofuran; 1.1: Sonogashira coupling;
DOI:10.1002/anie.200500484