1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III)

Base Information

• Chemical Name: 1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III)
• CAS No.: 855753-32-1
• Molecular Formula: C₈N₄NiS₄*C₁₆H₁₂BrFN
• Molecular Weight: 656.249
• Mol file: 855753-32-1.mol

Synonyms:1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III)

Chemical Property of 1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III)

There total 2 articles about 1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.5%

di(1-(4'-bromo-2'-fluorobenzyl)quinolinium) bis(meleonitriledithiolato)nickel(II) → 1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III) (855753-32-1)

Guidance literature:

With I₂; In acetonitrile; a soln. of I slowly addd to a soln. of Ni compd., stirred for 1 h; methanol added, kept overnight, crysts. filtered, washed (methanol), dried (vac.); elem. anal.;

DOI:10.1016/j.ica.2005.03.028

Reference yield:

1-(4'-bromo-2'-fluorobenzyl)quinolinium bromide (855753-43-4) → 1-(4'-bromo-2'-fluorobenzyl)quinolinium bis(meleonitriledithiolato)nickel(III) (855753-32-1)

Guidance literature:

Multi-step reaction with 2 steps

1: water

2: I₂ / acetonitrile

With I₂; In water; acetonitrile;

DOI:10.1016/j.ica.2005.03.028

upstream raw materials:

1-(4'-bromo-2'-fluorobenzyl)quinolinium bromide