[(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(P(CH₃)3)]

Base Information

• Chemical Name: [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(P(CH₃)3)]
• CAS No.: 801221-22-7
• Molecular Formula: C₃₀H₆₂BFeP₄
• Molecular Weight: 613.375
• Mol file: 801221-22-7.mol

Synonyms:[(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(P(CH₃)3)]

Chemical Property of [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(P(CH₃)3)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(P(CH₃)3)]

There total 3 articles about [(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(P(CH₃)3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

([PhB(CH2P(i-Pr)2)3]Fe(I))2(μ-N2) + trimethylphosphane (594-09-2) → [(C6H5B(CH2P(CH(CH3)2)2)3)Fe(P(CH3)3)] (801221-22-7)

Guidance literature:

In tetrahydrofuran; (N2); Schlenk technique; P ligand was added to soln. of Fe compd. in THF; soln. was stirred for 3 h; THF removed (vac.); triturated with petroleum ether;

DOI:10.1021/ic0488583

Reference yield: 78.0%

[(phenyl)B(CH2P(iPr)2)3(methyl)iron(II)] (801221-16-9) + trimethylphosphane (594-09-2) → [(C6H5B(CH2P(CH(CH3)2)2)3)Fe(P(CH3)3)] (801221-22-7)

Guidance literature:

With Na/Hg; In tetrahydrofuran; (N2); Schlenk technique; mixt. of Na/Hg amalgam and PMe3 in THF was stirred for several min; soln. of Fe compd. in THF was added at room temp.; soln. was stirred for 1.5 h; filtered; evapd.; extd. (Et2O); filtered; evapd.; stored at -25°C; elem. anal.;

DOI:10.1021/ic0488583

Reference yield:

{[PhBP3iPr]}FeCl (579444-62-5) → [(C6H5B(CH2P(CH(CH3)2)2)3)Fe(P(CH3)3)] (801221-22-7)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether; tetrahydrofuran

2: Na/Hg / tetrahydrofuran

With Na/Hg; In tetrahydrofuran; diethyl ether;

DOI:10.1021/ic0488583

upstream raw materials:

[(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)]

trimethylphosphane

{[PhBP₃^iPr]}FeCl

Refernces