[(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester

Base Information

Chemical Name:[(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester
CAS No.:128946-73-6
Molecular Formula:C₂₆H₃₄O₃Si
Molecular Weight:422.64
Hs Code.:

Synonyms:[(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester

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Chemical Property of [(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester

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Technology Process of [(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester

There total 4 articles about [(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 128946-71-4
(1R,6S)-6-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enol

: 78-39-7
Triethyl orthoacetate

: 128946-73-6
[(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester

Guidance literature:: propionic acid; In o-xylene; for 20h; Heating;
DOI:10.1016/S0040-4039(00)99249-9

Reference yield:

: 6426-26-2
(S)-cyclohex-2-en-1-ol

: 128946-73-6
[(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: MCPBA / CH₂Cl₂ / 0 °C

2: imidazole / dimethylformamide

3: LiNEt₂ / diethyl ether / 20 h / Heating

4: 83 percent / CH₃CH₂COOH / o-xylene / 20 h / Heating

With 1H-imidazole; lithium diethylamide; 3-chloro-benzenecarboperoxoic acid; propionic acid; In diethyl ether; dichloromethane; o-xylene; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)99249-9

Reference yield:

: 89064-04-0
(1S,2S,6R)-7-oxabicyclo[4.1.0]heptan-2-ol

: 128946-73-6
[(1S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-cyclohex-2-enyl]-acetic acid ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide

2: LiNEt₂ / diethyl ether / 20 h / Heating

3: 83 percent / CH₃CH₂COOH / o-xylene / 20 h / Heating

With 1H-imidazole; lithium diethylamide; propionic acid; In diethyl ether; o-xylene; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)99249-9