[(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester

Base Information

Chemical Name:[(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester
CAS No.:96999-69-8
Molecular Formula:C₂₁H₃₄O₄SSi₂
Molecular Weight:438.736
Hs Code.:

Synonyms:[(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester

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Chemical Property of [(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester

Chemical Property:

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Technology Process of [(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester

There total 1 articles about [(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 60989-29-9
2,2-Bis(trimethylsilyl)ethansaeure-methylester

: 93366-49-5
(+)-(R)-2-(p-tolylsulfinyl)cyclopent-2-enone

: 96999-69-8
[(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester

Guidance literature:: With n-butyllithium; N-cyclohexylisopropylamine; Yield given. Multistep reaction; 1.) THF, -78 deg C, 10 min., 2.) -78 deg C, 15 min;
DOI:10.1021/jo00214a041

Reference yield:

: 96999-69-8
[(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester

: 1211-29-6
Methyl jasmonate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) P₂I₄, 2.) KF / 1.) CH₂Cl₂, room temp., 10 min., 2.) methanol, room temp., 3 h

2: 1.) sodium hydride / 1.) glyme, 0 deg C, 25 min, 2a.) 0 deg C, 3h, 2b.) room temp., 12 h

3: 45 percent / W-2 Raney nickel / acetone / 3 h / Ambient temperature

With potassium fluoride; diphosphorus tetraiodide; W-2 Raney nickel; sodium hydride; In acetone;
DOI:10.1021/jo00214a041

Reference yield:

: 96999-69-8
[(R)-3-Oxo-2-(toluene-4-sulfinyl)-cyclopentyl]-bis-trimethylsilanyl-acetic acid methyl ester

: 2630-38-8
(S)-(-)-methyl 3-oxocyclopentylacetate

Guidance literature:: With potassium fluoride; aluminium amalgam; Yield given. Multistep reaction; 1.) THF, room temp., overnight, 2.) methanol, water, room temp., 3 h;
DOI:10.1021/jo00214a041