Technology Process of 3,3-dimethyl-1,1,5,5-tetraphenyl-2-aza-1,4-pentadiene
There total 8 articles about 3,3-dimethyl-1,1,5,5-tetraphenyl-2-aza-1,4-pentadiene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
di-tert-butyl nitroxide;
In
pentane;
at 20 ℃;
for 96h;
DOI:10.1021/jo034452g
- Guidance literature:
-
Multi-step reaction with 7 steps
1: SOCl2 / Heating
2: 4.9 g / sodium azide; tetrabutylammonium bromide / CH2Cl2; H2O / 2 h / 0 °C
3: toluene / 4 h / Heating
4: 2.77 g / aqueous HCl / 4 h / Heating
5: 80 percent / diethyl ether / 10 h / Heating
6: 51 percent / diethyl ether; hexane / 6 h / Heating
7: 73 percent / di-tert-butyliminoxyl radical / pentane / 96 h / 20 °C
With
hydrogenchloride; thionyl chloride; sodium azide; di-tert-butyl nitroxide; tetrabutylammomium bromide;
In
diethyl ether; hexane; dichloromethane; water; toluene; pentane;
3: Curtius reaction;
DOI:10.1021/jo034452g
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 4.9 g / sodium azide; tetrabutylammonium bromide / CH2Cl2; H2O / 2 h / 0 °C
2: toluene / 4 h / Heating
3: 2.77 g / aqueous HCl / 4 h / Heating
4: 80 percent / diethyl ether / 10 h / Heating
5: 51 percent / diethyl ether; hexane / 6 h / Heating
6: 73 percent / di-tert-butyliminoxyl radical / pentane / 96 h / 20 °C
With
hydrogenchloride; sodium azide; di-tert-butyl nitroxide; tetrabutylammomium bromide;
In
diethyl ether; hexane; dichloromethane; water; toluene; pentane;
2: Curtius reaction;
DOI:10.1021/jo034452g
