C₂₂H₂₆O₆Si

Base Information

• Chemical Name: C₂₂H₂₆O₆Si
• CAS No.: 1350623-72-1
• Molecular Formula: C₂₂H₂₆O₆Si
• Molecular Weight: 414.53
• Mol file: 1350623-72-1.mol

Synonyms:C₂₂H₂₆O₆Si

Chemical Property of C₂₂H₂₆O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₂H₂₆O₆Si

There total 12 articles about C₂₂H₂₆O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

C31H46O6Si2 (1350623-70-9) → C22H26O6Si (1350623-72-1)

Guidance literature:

With pyridine hydrogenfluoride; In tetrahydrofuran; at 0 ℃;

DOI:10.1021/ol2028256

Reference yield:

C36H66O5Si3 → C22H26O6Si (1350623-72-1)

Guidance literature:

Multi-step reaction with 6 steps

1.1: trifluoroacetic acid / dichloromethane / 24 h / 0 - 20 °C / Molecular sieve; Inert atmosphere

2.1: pyridine hydrogenfluoride / tetrahydrofuran / 4.8 h / -5 °C

3.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 9.6 h / 20 °C / Inert atmosphere

4.1: zinc(II) chloride / tetrahydrofuran; diethyl ether / 0.25 h / -78 °C / Inert atmosphere

4.2: 0.75 h / -78 °C / Inert atmosphere

5.1: trifluoroacetic acid / diethyl ether / 10 h / 0 °C

6.1: pyridine hydrogenfluoride / tetrahydrofuran / 0 °C

With pyridine hydrogenfluoride; trifluoroacetic acid; zinc(II) chloride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; dichloromethane; dimethyl sulfoxide;

DOI:10.1021/ol2028256

Reference yield:

C27H44O4Si2 (1350623-69-6) → C22H26O6Si (1350623-72-1)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 9.6 h / 20 °C / Inert atmosphere

2.1: zinc(II) chloride / tetrahydrofuran; diethyl ether / 0.25 h / -78 °C / Inert atmosphere

2.2: 0.75 h / -78 °C / Inert atmosphere

3.1: trifluoroacetic acid / diethyl ether / 10 h / 0 °C

4.1: pyridine hydrogenfluoride / tetrahydrofuran / 0 °C

With pyridine hydrogenfluoride; trifluoroacetic acid; zinc(II) chloride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; diethyl ether; dimethyl sulfoxide;

DOI:10.1021/ol2028256

upstream raw materials:

C₂₇H₄₄O₄Si₂

C₃₁H₅₆O₄Si₂

C₃₁H₅₆O₅Si₂

C₃₆H₆₄O₄Si₃

Downstream raw materials:

C₂₈H₃₈O₅Si₂

C₂₁H₂₂O₅S₂

C₁₉H₂₀O₄

C₂₅H₃₂O₅Si