Cyclopropanecarboxaldehyde, 1-methyl-2-phenyl-, (1R,2S)- (9CI)

Base Information

Chemical Name:Cyclopropanecarboxaldehyde, 1-methyl-2-phenyl-, (1R,2S)- (9CI)
CAS No.:443889-62-1
Molecular Formula:C₁₁H₁₂O
Molecular Weight:160.216
Hs Code.:
Mol file:443889-62-1.mol

Synonyms:Cyclopropanecarboxaldehyde, 1-methyl-2-phenyl-, (1R,2S)- (9CI)

Suppliers and Price of Cyclopropanecarboxaldehyde, 1-methyl-2-phenyl-, (1R,2S)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Cyclopropanecarboxaldehyde, 1-methyl-2-phenyl-, (1R,2S)- (9CI)

Chemical Property:

Boiling Point:128 - 130 °C (15 mmHg)
PSA：17.07000
LogP:2.37910

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Cyclopropanecarboxaldehyde, 1-methyl-2-phenyl-, (1R,2S)- (9CI)

There total 5 articles about Cyclopropanecarboxaldehyde, 1-methyl-2-phenyl-, (1R,2S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 178941-27-0
(4R,5R)-2-((1R,2S)-1-Methyl-2-phenyl-cyclopropyl)-[1,3]dioxolane-4,5-dicarboxylic acid diisopropyl ester

: 443889-62-1,175788-15-5
1-Methyl-2-cis-phenyl-cyclopropan-carbaldehyd (1ref)

Guidance literature:: With perchloric acid; In tetrahydrofuran; for 3h; Yield given; Ambient temperature;
DOI:10.1039/P19960001243

Reference yield:

: 178941-26-9
(4R,5R)-2-((E)-1-Methyl-2-phenyl-vinyl)-[1,3]dioxolane-4,5-dicarboxylic acid diisopropyl ester

: 443889-62-1,175788-15-5
1-Methyl-2-cis-phenyl-cyclopropan-carbaldehyd (1ref)

Guidance literature:: Multi-step reaction with 2 steps

1: 40 percent / Et₂Zn / hexane / 1.) -10 to 0 deg C, 2 h, 2.) r.t., 1 h

2: 10percent aq. HClO₄ / tetrahydrofuran / 3 h / Ambient temperature

With perchloric acid; diethylzinc; In tetrahydrofuran; hexane;
DOI:10.1039/P19960001243

Reference yield:

: 15174-47-7
α-methyl-trans-cinnamaldehyde

: 443889-62-1,175788-15-5
1-Methyl-2-cis-phenyl-cyclopropan-carbaldehyd (1ref)

Guidance literature:: Multi-step reaction with 3 steps

1: 18 percent / (+)-camphorsulfonic acid / benzene / Heating

2: 40 percent / Et₂Zn / hexane / 1.) -10 to 0 deg C, 2 h, 2.) r.t., 1 h

3: 10percent aq. HClO₄ / tetrahydrofuran / 3 h / Ambient temperature

With perchloric acid; diethylzinc; (+)-10-camphorsulfonic acid; In tetrahydrofuran; hexane; benzene;
DOI:10.1039/P19960001243