(3S,5R,6S,9R)-3,9-dihydroxymegastigman

Base Information

• Chemical Name: (3S,5R,6S,9R)-3,9-dihydroxymegastigman
• CAS No.: 242799-88-8
• Molecular Formula: C₁₃H₂₆O₂
• Molecular Weight: 214.348
• Mol file: 242799-88-8.mol

Synonyms:(3S,5R,6S,9R)-3,9-dihydroxymegastigman

Chemical Property of (3S,5R,6S,9R)-3,9-dihydroxymegastigman

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (3S,5R,6S,9R)-3,9-dihydroxymegastigman

There total 5 articles about (3S,5R,6S,9R)-3,9-dihydroxymegastigman which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.4%

(3S,5R,6S,9R)-megastigman-3,9-diol 3-O-α-L-arabinopyranosyl(1->6)-β-D-glucopyranoside (1039646-50-8,168009-96-9) → (3S,5R,6S,9R)-3,9-dihydroxymegastigman (242799-88-8)

Guidance literature:

With naringinase; water; at 40 ℃; for 48h; pH=3.8; aq. acetate buffer; Enzymatic reaction;

DOI:10.1248/cpb.56.547

Reference yield: 85.0%

(3S,5R,6S,9R)-megastigman-3,9-diol 9-O-β-D-apiofuranosyl(1->6)-β-D-glucopyranoside → (3S,5R,6S,9R)-3,9-dihydroxymegastigman (242799-88-8)

Guidance literature:

In water; at 37 ℃; for 40h; hesperidinase;

DOI:10.1248/cpb.43.754

Reference yield: 60.0%

trans-(3S,5R,6R,9R)-megastigm-7-en-3,9-diol → (3S,5R,6S,9R)-3,9-dihydroxymegastigman (242799-88-8)

Guidance literature:

With hydrogen; palladium on activated charcoal; In methanol; at 20 ℃; for 1h;

DOI:10.1248/cpb.55.435

upstream raw materials:

alangionoside G

(3S,5R,6S,9R)-megastigman-3,9-diol 3-O-α-L-arabinopyranosyl(1->6)-β-D-glucopyranoside