tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane

Base Information

Chemical Name:tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane
CAS No.:795282-22-3
Molecular Formula:C₂₈H₅₄OSi
Molecular Weight:434.822
Hs Code.:

Synonyms:tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane

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Chemical Property of tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane

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Technology Process of tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane

There total 2 articles about tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 7103-09-5
4-but-1-enylmagnesium bromide

: 2,2-Dimethyl-propionic acid (E)-(S)-7-(tert-butyl-dimethyl-silanyloxy)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-hept-2-enyl ester

: 795282-22-3
tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane

Guidance literature:: 4-but-1-enylmagnesium bromide; With CuCN; In diethyl ether; at -10 ℃; for 0.166667h;

2,2-Dimethyl-propionic acid (E)-(S)-7-(tert-butyl-dimethyl-silanyloxy)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-hept-2-enyl ester; In diethyl ether; at 20 ℃; for 1.5h;
DOI:10.1021/ja046084j

Reference yield:

: 795280-02-3
(E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-3-methyl-hept-2-en-1-ol

: 795282-22-3
tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 98 percent / triethylamine / CH₂Cl₂ / 12 h / 20 °C

2.1: CuCN / diethyl ether / 0.17 h / -10 °C

2.2: 41 percent / diethyl ether / 1.5 h / 20 °C

With triethylamine; In diethyl ether; dichloromethane;
DOI:10.1021/ja046084j

Reference yield: 70.0%

: 795282-22-3
tert-Butyl-{(R)-5-[(E)-2-((1S,2S,5R)-2-isopropyl-5-methyl-cyclohexyl)-vinyl]-5-methyl-non-8-enyloxy}-dimethyl-silane

: tert-butyl-dimethyl-[4-(1-methyl-cyclopent-3-enyl)-butoxy]-silane

: tert-butyl-dimethyl-[4-(1-methyl-cyclopent-2-enyl)-butoxy]-silane

: C₅₄H₁₀₄O₂Si₂

: (1S,2S,4R)-1-Isopropyl-4-methyl-2-vinylcyclohexane

Guidance literature:: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene](benzylidene)Ru(II) dichloride; In dichloromethane; for 3h; Heating;
DOI:10.1139/V06-095