5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde

Base Information

Chemical Name:5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde
CAS No.:86902-40-1
Molecular Formula:C₁₆H₂₆O₃
Molecular Weight:266.381
Hs Code.:

Synonyms:5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde

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Chemical Property of 5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde

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Technology Process of 5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde

There total 3 articles about 5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 86902-70-7
4-(1,1-dimethylethyl)-2-<<(trimethylsilyl)oxy>methylene>-1-<α-(methoxymethoxy)prop-2-enyl>cyclohexan-1-ol

: 86902-40-1
5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde

Guidance literature:: With pyridinium p-toluenesulfonate; In dichloromethane; at 23 ℃; for 0.166667h;
DOI:10.1021/jo00169a056

Reference yield:

: 22252-96-6
4-(tert-butyl)-2-(hydroxymethylene)cyclohexan-1-one

: 86902-40-1
5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: Me₃N / tetrahydrofuran

2: 1.) sec-BuLi, anh. zinc chloride / 1.) THF, -78 deg C, 10 min, 2.) -78 deg C, 10 min, -78 deg C to room temp., 10 min

3: pyridinium tosylate / CH₂Cl₂ / 0.17 h / 23 °C

With sec.-butyllithium; pyridinium p-toluenesulfonate; zinc(II) chloride; trimethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00169a056

Reference yield:

: 83458-65-5
2-<<(trimethylsilyl)oxy>methylene>-4-(1,1-dimethylethyl)cyclohexanone

: 86902-40-1
5-(1,1-dimethylethyl)-2-<α-(methoxymethoxy)prop-2-enyl>cyclohex-1-enecarboxaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) sec-BuLi, anh. zinc chloride / 1.) THF, -78 deg C, 10 min, 2.) -78 deg C, 10 min, -78 deg C to room temp., 10 min

2: pyridinium tosylate / CH₂Cl₂ / 0.17 h / 23 °C

With sec.-butyllithium; pyridinium p-toluenesulfonate; zinc(II) chloride; In dichloromethane;
DOI:10.1021/jo00169a056