(1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one

Base Information

Chemical Name:(1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one
CAS No.:72581-74-9
Molecular Formula:C₁₇H₂₀N₂O₆S
Molecular Weight:380.422
Hs Code.:

Synonyms:(1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one

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Chemical Property of (1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one

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Technology Process of (1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one

There total 6 articles about (1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2403-62-5
p-nitrobenzaldehyde diethyl acetal

: 72581-74-9
(1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / 165 °C

2: m-chloroperbenzoic acid, NaHCO₃ / CHCl₃ / 3.5 h / Ambient temperature

With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In chloroform;
DOI:10.1021/ja00384a028

Reference yield:

: 3144-16-9,61380-66-3
(1S)-10-camphorsulfonic acid

: 72581-74-9
(1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: thionyl chloride / 1.) room temperature, 10 min, 2.) reflux, 1.5 h

2: 8.2 g / ammonia / CHCl₃ / 0.67 h

3: 78 percent / 165 °C

4: m-chloroperbenzoic acid, NaHCO₃ / CHCl₃ / 3.5 h / Ambient temperature

With thionyl chloride; ammonia; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In chloroform;
DOI:10.1021/ja00384a028

Reference yield:

: 21286-54-4
(+)-(1S)-Campher-10-sulfonsaeure-chlorid

: 72581-74-9
(1S,4R)-7,7-Dimethyl-1-[(2S,3S)-3-(4-nitro-phenyl)-oxaziridine-2-sulfonylmethyl]-bicyclo[2.2.1]heptan-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 8.2 g / ammonia / CHCl₃ / 0.67 h

2: 78 percent / 165 °C

3: m-chloroperbenzoic acid, NaHCO₃ / CHCl₃ / 3.5 h / Ambient temperature

With ammonia; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In chloroform;
DOI:10.1021/ja00384a028