2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate

Base Information

Chemical Name:2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate
CAS No.:685104-34-1
Molecular Formula:C₃₂H₃₂Cl₃NO₁₄
Molecular Weight:760.963
Hs Code.:

Synonyms:2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate

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Chemical Property of 2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate

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Technology Process of 2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate

There total 2 articles about 2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 545-06-2
trichloroacetonitrile

: C₃₀H₃₂O₁₄

: 685104-34-1
2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1002/ejoc.200300580

Reference yield:

: C₃₇H₃₈O₁₄

: 685104-34-1
2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1: 37 percent / hydrogen / Pd/C / ethyl acetate; aq. ethanol / 24 h / 40 °C / 38002.6 Torr

2: 89 percent / DBU / CH₂Cl₂ / 0.5 h / 20 °C

With hydrogen; 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium on activated charcoal; In ethanol; dichloromethane; ethyl acetate;
DOI:10.1002/ejoc.200300580

Reference yield: 88.0%

: 127753-95-1
ethyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside

: 685104-34-1
2,4-di-O-benzoyl-3-O-(2,3,3'-tri-O-acetyl-β-D-apiofuranosyl)-α-D-xylopyranosyl trichloroacetimidate

: 685104-35-2
ethyl 2,3,3'-tri-O-acetyl-β-D-apiofuranosyl-(1->3)-2,4-di-O-benzoyl-β-D-xylopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In dichloromethane; at -50 - 20 ℃; for 45h;
DOI:10.1002/ejoc.200300580