3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate

Base Information

Chemical Name:3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate
CAS No.:157520-44-0
Molecular Formula:C₁₆H₂₃F₃O₅S
Molecular Weight:384.417
Hs Code.:

Synonyms:3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate

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Chemical Property of 3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate

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Technology Process of 3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate

There total 4 articles about 3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: N-(5-chloro-2-pyridyl)triflylamide

: 2-methoxycarbonyl-2-(3'-methylbut-3'-enyl)-5,5-dimethylcyclohexanone

: 157520-44-0
3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate

Guidance literature:: 2-methoxycarbonyl-2-(3'-methylbut-3'-enyl)-5,5-dimethylcyclohexanone; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

N-(5-chloro-2-pyridyl)triflylamide; In tetrahydrofuran; hexane; at -78 ℃; for 3h;
DOI:10.1016/S0040-4020(97)00754-0

Reference yield: 67.0%

: 145100-51-2
N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide

: 2-methoxycarbonyl-2-(3'-methylbut-3'-enyl)-5,5-dimethylcyclohexanone

: 157520-44-0
3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate

Guidance literature:: 2-methoxycarbonyl-2-(3'-methylbut-3'-enyl)-5,5-dimethylcyclohexanone; With potassium hexamethylsilazane; In tetrahydrofuran; at -78 - 0 ℃; for 1.5h; Inert atmosphere;

N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;
DOI:10.1002/anie.201913730

Reference yield:

: C₁₄H₂₂O₄

: 157520-44-0
3,3-dimethyl-6-(3'-methylbut-3'-enyl)-6-methoxycarbonylcyclohexenyl triflate

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran / 0.25 h / 0 °C / Inert atmosphere

1.2: 2 h / 0 °C / Inert atmosphere

2.1: potassium hexamethylsilazane / tetrahydrofuran / 1.5 h / -78 - 0 °C / Inert atmosphere

2.2: 1 h / -78 °C / Inert atmosphere

With n-butyllithium; potassium hexamethylsilazane; In tetrahydrofuran;
DOI:10.1002/anie.201913730