dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0)

Base Information

• Chemical Name: dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0)
• CAS No.: 67663-92-7
• Molecular Formula: C₂₇H₂₅FeO₅P
• Molecular Weight: 516.313
• Mol file: 67663-92-7.mol

Synonyms:dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0)

Chemical Property of dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0)

There total 3 articles about dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

triphenyl phosphite (101-02-0) + tricarbonyl(η-3-cyclohepta-1,3-diene)iron (40674-86-0) → dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0) (67663-92-7)

Guidance literature:

In dibutyl ether; refluxed for 4 h;

DOI:10.1351/pac198355111767

Reference yield: 63.0%

(benzylideneacetone)dicarbonyl(triphenyl phosphite)iron(0) (93984-14-6,59464-78-7,116325-54-3) + Cyclohepta-1,3-diene (876938-53-3) → dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0) (67663-92-7)

Guidance literature:

In benzene; N2-atmosphere; refluxing of Fe-complex with 10 equiv. of diene (6 h); chromy. (SiO2, C6H6);

DOI:10.1039/DT9780000369

Reference yield:

tricarbonyl(η-3-cyclohepta-1,3-diene)iron (40674-86-0) → dicarbonyl(η-cyclohepta-1,3-diene)(triphenyl phosphite)iron(0) (67663-92-7)

Guidance literature:

With P(OC₆H₅)3; In dibutyl ether; Irradiation (UV/VIS); react. under N2, photolytical react. of Fe-complex with phosphite in soln.; recrystd. (petroleum ether); elem. anal.;

DOI:10.1016/0022-328X(91)86199-Z

upstream raw materials:

triphenyl phosphite

tricarbonyl(η-3-cyclohepta-1,3-diene)iron

(benzylideneacetone)dicarbonyl(triphenyl phosphite)iron⁽⁰⁾

Cyclohepta-1,3-diene

Downstream raw materials:

dicarbonyl(1-5-η-cycloheptadienylium)(triphenyl phosphite)iron(0) tetrafluoroborate