methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

Base Information

Chemical Name:methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate
CAS No.:1588513-34-1
Molecular Formula:C₂₅H₂₅N₅O₆
Molecular Weight:491.503
Hs Code.:

methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

Synonyms:methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

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Chemical Property of methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

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Technology Process of methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

There total 6 articles about methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1588513-04-5
C₃₀H₃₂N₇O₆⁽¹⁺⁾*BF₄^(1-)

: 1588513-34-1
methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

Guidance literature:: With ammonia; In methanol; at 20 ℃; for 8h; regioselective reaction; Inert atmosphere;
DOI:10.1021/co400159z

Reference yield:

: 1410063-79-4
C₁₉H₂₄N₅O₃⁽¹⁺⁾*BF₄^(1-)

: 1588513-34-1
methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: piperidine / toluene / 18 h / Inert atmosphere; Reflux; Microwave irradiation

1.2: 24 h / Inert atmosphere; Reflux; Microwave irradiation

2.1: ammonia / methanol / 8 h / 20 °C / Inert atmosphere

With piperidine; ammonia; In methanol; toluene;
DOI:10.1021/co400159z

Reference yield:

: 453-71-4
3-nitro-4-fluorobenzoic acid

: 1588513-34-1
methyl 3-allyl-2-[4-(nitrooxy)phenyl]-4-oxo-10-(tetrahydro-2-furanylmethyl)-2,3,4,10-tetrahydrobenzo[4,5]imidazo[1,2-a][1,3,5]triazin-7-ylcarboxylate

Guidance literature:: Multi-step reaction with 6 steps

1.1: dicyclohexyl-carbodiimide; dmap / acetonitrile / 24 h / Inert atmosphere; Reflux

2.1: acetonitrile / 4 h / Inert atmosphere; Reflux

3.1: ammonium formate; zinc / methanol / 0.5 h / Inert atmosphere; Reflux

4.1: dichloromethane / 12 h / Inert atmosphere; Reflux

5.1: piperidine / toluene / 18 h / Inert atmosphere; Reflux; Microwave irradiation

5.2: 24 h / Inert atmosphere; Reflux; Microwave irradiation

6.1: ammonia / methanol / 8 h / 20 °C / Inert atmosphere

With piperidine; dmap; ammonia; ammonium formate; dicyclohexyl-carbodiimide; zinc; In methanol; dichloromethane; toluene; acetonitrile;
DOI:10.1021/co400159z