methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

Base Information

Chemical Name:methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate
CAS No.:93292-45-6
Molecular Formula:C₃₀H₄₂O₅Si
Molecular Weight:510.746
Hs Code.:

Synonyms:methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

Suppliers and Price of methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

There total 6 articles about methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 93292-43-4
(Z)-(S)-8-(tert-Butyl-diphenyl-silanyloxy)-8-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-oct-5-enoic acid

: 93292-45-6
methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

Guidance literature:: In methanol; diethyl ether; for 0.166667h; Ambient temperature;
DOI:10.1021/jo00375a009

Reference yield:

: 17814-85-6
(4-carboxybutyl)triphenylphosphonium bromide

: 93292-45-6
methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

Guidance literature:: Multi-step reaction with 3 steps

1: lithium hexamethyldisilazide (LiHMDS) / tetrahydrofuran; hexamethylphosphoric acid triamide

With lithium hexamethyldisilazane; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/0040-4039(84)80003-9

Reference yield:

: 93292-42-3
2-deoxy-3-O-(tert-butyldiphenylsilyl)-4,5-bis-O-(1-methylethylidene)-D-erythro-pentose

: 93292-45-6
methyl 8(S)-<(tert-butyldiphenylsilyl)oxy>-9,10-(isopropylidenedioxy)-5(Z)-decenoate

Guidance literature:: Multi-step reaction with 2 steps

1: 57 percent / tetrahydrofuran / 1.) -78 deg C, 30 min, 2.) RT, 30 min;

2: 100 percent / methanol; diethyl ether / 0.17 h / Ambient temperature

In tetrahydrofuran; methanol; diethyl ether;
DOI:10.1021/jo00375a009