tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane

Base Information

Chemical Name:tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane
CAS No.:123331-86-2
Molecular Formula:C₁₆H₂₈OSi
Molecular Weight:264.483
Hs Code.:

Synonyms:tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane

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Chemical Property of tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane

Chemical Property:

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Technology Process of tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane

There total 1 articles about tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 5503-12-8
L-perillaldehyde

: 123331-86-2
tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃;
DOI:10.1021/jo00284a011

Reference yield:

: 123331-86-2
tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane

: 123331-88-4,136954-93-3
(R)-4-(2-Methyl-oxiranyl)-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: m-chloroperbenzoic acid, aq. NaHCO₃ / CH₂Cl₂ / 0.5 h / Ambient temperature

2: NaIO₄, HF / H₂O; acetonitrile / 2 h / Ambient temperature

3: 85 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 10 h

With sodium periodate; hydrogen fluoride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water; acetonitrile;
DOI:10.1021/jo00024a031

Reference yield:

: 123331-86-2
tert-Butyl-[(R)-4-isopropenyl-cyclohex-2-en-(E)-ylidenemethoxy]-dimethyl-silane

: 123331-89-5,123408-94-6,137036-88-5,137036-89-6
(4R)-1-(1,3-dithianyl)-4-(2-propenylepoxy)-2-cyclohexen-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: m-chloroperbenzoic acid, aq. NaHCO₃ / CH₂Cl₂ / 0.5 h / Ambient temperature

2: NaIO₄, HF / H₂O; acetonitrile / 2 h / Ambient temperature

3: 85 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 10 h

4: 1) n-BuLi / 1) hexane, THF, 1.5 h, -35 to -25 deg C, 2) THF, room temperature, 30 min

With sodium periodate; n-butyllithium; hydrogen fluoride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water; acetonitrile;
DOI:10.1021/jo00024a031