(S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

Base Information

Chemical Name:(S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate
CAS No.:1365547-86-9
Molecular Formula:C₂₈H₃₂N₂O₃S
Molecular Weight:476.64
Hs Code.:

Synonyms:(S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

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Chemical Property of (S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

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Technology Process of (S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

There total 5 articles about (S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1365548-30-6
(S(S),2S,2'R)-ethyl 2-(diphenylmethyleneamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

: 1365547-86-9
(S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

Guidance literature:: With sodium cyanoborohydride; acetic acid; In methanol; at 20 ℃; for 6h;
DOI:10.1039/c2ob06637h

Reference yield:

: 1365547-75-6
(S_S)-α-chloro-N-p-toluenesulfinyl isobutyraldimine

: 1365547-86-9
(S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium; diisopropylamine / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere

1.2: 0.08 h / -90 °C / Inert atmosphere

2.1: potassium carbonate / acetone / 24 h / 20 °C / Reflux

3.1: sodium cyanoborohydride; acetic acid / methanol / 6 h / 20 °C

With n-butyllithium; sodium cyanoborohydride; potassium carbonate; acetic acid; diisopropylamine; In tetrahydrofuran; methanol; hexane; acetone; 1.2: Mannich type reaction;
DOI:10.1039/c2ob06637h

Reference yield:

: 1365548-18-0
(S(S),2S,3R)-ethyl 2-(diphenylmethyleneamino)-4-chloro-4-methyl-3-(p-toluenesulfinylamino)pentanoate

: 1365547-86-9
(S(S),2S,2'R)-ethyl 2-(diphenylmethylamino)-2-[3,3-dimethyl-1-(p-toluenesulfinyl)aziridin-2-yl]acetate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / acetone / 24 h / 20 °C / Reflux

2: sodium cyanoborohydride; acetic acid / methanol / 6 h / 20 °C

With sodium cyanoborohydride; potassium carbonate; acetic acid; In methanol; acetone;
DOI:10.1039/c2ob06637h