5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine

Base Information

• Chemical Name: 5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine
• CAS No.: 1383687-57-7
• Molecular Formula: C₁₆H₂₄N₁₆O₇
• Molecular Weight: 552.47
• Mol file: 1383687-57-7.mol

Synonyms:5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine

Chemical Property of 5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine

There total 7 articles about 5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazido-6,3',4'-tri-O-acetylneamine (1383687-91-9) → 5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine (1383687-57-7)

Guidance literature:

5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazido-6,3',4'-tri-O-acetylneamine; With sodium methylate; In methanol; at 20 ℃; Inert atmosphere;

In methanol;

DOI:10.1039/c2ob07065k

Reference yield:

3-azidopropylamine (88192-19-2) + 5,6-[carbonylbis(oxy)]-3',4'-di-O-acetyl-1,3,2',6'-tetraazidoneamine (1383687-47-5) → 6-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine (1383687-58-8) + 5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine (1383687-57-7)

Guidance literature:

3-azidopropylamine; 5,6-[carbonylbis(oxy)]-3',4'-di-O-acetyl-1,3,2',6'-tetraazidoneamine; In dichloromethane; at 20 ℃; for 2h;

With sodium methylate; In methanol; at 20 ℃;

In methanol;

DOI:10.1039/c2ob07065k

Reference yield:

1,3,2′,6′-tetraazido-6,3′,4′-tri-O-acetylneamine (182554-04-7) → 5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazidoneamine (1383687-57-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: pyridine / dichloromethane / Inert atmosphere

2.1: dichloromethane / 2 h / 20 °C

3.1: sodium methylate / methanol / 20 °C / Inert atmosphere

3.2: Amberlyst_.(R). 15,20-50 mesh, H⁺

With pyridine; sodium methylate; In methanol; dichloromethane;

DOI:10.1039/c2ob07065k

upstream raw materials:

3-azidopropylamine

5,6-[carbonylbis(oxy)]-3',4'-di-O-acetyl-1,3,2',6'-tetraazidoneamine

5-[(chlorocarbonyl)oxy]-1,3,2',6'-tetraazido-6,3',4'-tri-O-acetylneamine

5-[[(3-azidopropylamino)carbonyl]oxy]-1,3,2',6'-tetraazido-6,3',4'-tri-O-acetylneamine