Technology Process of C26H40O5Si
There total 3 articles about C26H40O5Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
[Rh(nbd)(diphos-4)]BF4; hydrogen;
In
tetrahydrofuran;
at 20 ℃;
for 2h;
under 31029.7 Torr;
DOI:10.1021/ja413106t
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere
1.2: 1.5 h / 0 °C / Inert atmosphere
2.1: selenium(IV) oxide; tert.-butylhydroperoxide / dichloromethane; water / 16 h / 20 °C / Inert atmosphere
3.1: [Rh(nbd)(diphos-4)]BF4; hydrogen / tetrahydrofuran / 2 h / 20 °C / 31029.7 Torr
With
tert.-butylhydroperoxide; selenium(IV) oxide; n-butyllithium; [Rh(nbd)(diphos-4)]BF4; hydrogen;
In
tetrahydrofuran; hexane; dichloromethane; water;
1.1: |Wittig Olefination / 1.2: |Wittig Olefination;
DOI:10.1021/ja413106t
- Guidance literature:
-
Multi-step reaction with 2 steps
1: selenium(IV) oxide; tert.-butylhydroperoxide / dichloromethane; water / 16 h / 20 °C / Inert atmosphere
2: [Rh(nbd)(diphos-4)]BF4; hydrogen / tetrahydrofuran / 2 h / 20 °C / 31029.7 Torr
With
tert.-butylhydroperoxide; selenium(IV) oxide; [Rh(nbd)(diphos-4)]BF4; hydrogen;
In
tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ja413106t