toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester

Base Information

Chemical Name:toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester
CAS No.:529510-51-8
Molecular Formula:C₁₈H₃₂O₄SSi
Molecular Weight:372.601
Hs Code.:

toluene-4-sulfonic acid 2-(<i>tert</i>-butyl-dimethyl-silanyloxy)-pentyl ester

Synonyms:toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester

Suppliers and Price of toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester

There total 2 articles about toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 69739-34-0
t-butyldimethylsiyl triflate

: 529510-44-9
(R)-(+)-2-hydroxypentyl tosylate

: 529510-51-8
toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -50 - 20 ℃; for 48h;
DOI:10.1016/S0040-4039(03)00110-2

Reference yield:

: 117120-69-1
(2S,3S)-(-)-1-(Tosyloxy)-2,3-epoxypentan

: 529510-51-8
toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-pentyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: MgI₂ / toluene / 1 h / -60 °C

1.2: 80 percent / Bu₃SnH; AIBN / toluene / 1 h / Heating

2.1: 90 percent / 2,6-lutidine / CH₂Cl₂ / 48 h / -50 - 20 °C

With 2,6-dimethylpyridine; magnesium iodide; In dichloromethane; toluene;
DOI:10.1016/S0040-4039(03)00110-2