C₆₈H₉₇NO₆Si

Base Information

• Chemical Name: C₆₈H₉₇NO₆Si
• CAS No.: 1332507-49-9
• Molecular Formula: C₆₈H₉₇NO₆Si
• Molecular Weight: 1052.61
• Mol file: 1332507-49-9.mol

Synonyms:C₆₈H₉₇NO₆Si

Chemical Property of C₆₈H₉₇NO₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₈H₉₇NO₆Si

There total 7 articles about C₆₈H₉₇NO₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydroquinone (123-31-9,8027-02-9) → C68H97NO6Si (1332507-49-9)

Guidance literature:

Multi-step reaction with 8 steps

1.1: potassium carbonate; potassium iodide / N,N-dimethyl-formamide / 70 - 80 °C

2.1: bromine; sodium acetate; acetic acid / chloroform / 30 °C

2.2: 20 - 30 °C

3.1: potassium iodate; sulfuric acid; water; iodine; acetic acid / tetrachloromethane / 5.5 h / Reflux

4.1: piperidine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / tetrahydrofuran / 20 °C / Inert atmosphere

4.2: 16 h / 50 °C / Inert atmosphere

5.1: potassium carbonate / tetrahydrofuran; methanol / 3 h / 20 °C

6.1: piperidine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / tetrahydrofuran / 20 °C / Inert atmosphere

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2.5 h / 20 °C

8.1: ethylmagnesium bromide / tetrahydrofuran / 2 h / 20 °C

With piperidine; bis-triphenylphosphine-palladium(II) chloride; potassium iodate; copper(l) iodide; sulfuric acid; ethylmagnesium bromide; tetrabutyl ammonium fluoride; water; bromine; iodine; sodium acetate; potassium carbonate; acetic acid; triphenylphosphine; potassium iodide; In tetrahydrofuran; methanol; tetrachloromethane; chloroform; N,N-dimethyl-formamide; 1.1: Williamson synthesis / 4.1: Sonogashira coupling / 6.1: Sonogashira coupling;

DOI:10.1039/c1cc12435h

Reference yield:

1-bromo-hexane (111-25-1) → C68H97NO6Si (1332507-49-9)

Guidance literature:

Multi-step reaction with 8 steps

1.1: potassium carbonate; potassium iodide / N,N-dimethyl-formamide / 70 - 80 °C

2.1: bromine; sodium acetate; acetic acid / chloroform / 30 °C

2.2: 20 - 30 °C

3.1: potassium iodate; sulfuric acid; water; iodine; acetic acid / tetrachloromethane / 5.5 h / Reflux

4.1: piperidine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / tetrahydrofuran / 20 °C / Inert atmosphere

4.2: 16 h / 50 °C / Inert atmosphere

5.1: potassium carbonate / tetrahydrofuran; methanol / 3 h / 20 °C

6.1: piperidine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / tetrahydrofuran / 20 °C / Inert atmosphere

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2.5 h / 20 °C

8.1: ethylmagnesium bromide / tetrahydrofuran / 2 h / 20 °C

With piperidine; bis-triphenylphosphine-palladium(II) chloride; potassium iodate; copper(l) iodide; sulfuric acid; ethylmagnesium bromide; tetrabutyl ammonium fluoride; water; bromine; iodine; sodium acetate; potassium carbonate; acetic acid; triphenylphosphine; potassium iodide; In tetrahydrofuran; methanol; tetrachloromethane; chloroform; N,N-dimethyl-formamide; 1.1: Williamson synthesis / 4.1: Sonogashira coupling / 6.1: Sonogashira coupling;

DOI:10.1039/c1cc12435h

Reference yield:

1,4-dihexyloxybenzene (67399-93-3) → C68H97NO6Si (1332507-49-9)

Guidance literature:

Multi-step reaction with 7 steps

1.1: bromine; sodium acetate; acetic acid / chloroform / 30 °C

1.2: 20 - 30 °C

2.1: potassium iodate; sulfuric acid; water; iodine; acetic acid / tetrachloromethane / 5.5 h / Reflux

3.1: piperidine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / tetrahydrofuran / 20 °C / Inert atmosphere

3.2: 16 h / 50 °C / Inert atmosphere

4.1: potassium carbonate / tetrahydrofuran; methanol / 3 h / 20 °C

5.1: piperidine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine / tetrahydrofuran / 20 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2.5 h / 20 °C

7.1: ethylmagnesium bromide / tetrahydrofuran / 2 h / 20 °C

With piperidine; bis-triphenylphosphine-palladium(II) chloride; potassium iodate; copper(l) iodide; sulfuric acid; ethylmagnesium bromide; tetrabutyl ammonium fluoride; water; bromine; iodine; sodium acetate; potassium carbonate; acetic acid; triphenylphosphine; In tetrahydrofuran; methanol; tetrachloromethane; chloroform; 3.1: Sonogashira coupling / 5.1: Sonogashira coupling;

DOI:10.1039/c1cc12435h

upstream raw materials:

1-bromo-hexane

1,4-dihexyloxybenzene

hydroquinone

2-bromo-1,4-bis(hexyloxy)benzene

Downstream raw materials:

C₁₇₅H₂₂₃N₃O₁₂Si₂