6-NITRO-1-HEXENE, 97

Base Information

• Chemical Name: 6-NITRO-1-HEXENE, 97
• CAS No.: 4812-17-3
• Molecular Formula: C6H11 N O2
• Molecular Weight: 129.159
• Mol file: 4812-17-3.mol

Synonyms:1-Nitrohex-5-ene;6-Nitro-1-hexene

Chemical Property of 6-NITRO-1-HEXENE, 97

Chemical Property:

• Refractive Index: n20/D 1.444(lit.)
• Boiling Point: 195 °C(lit.)
• PKA: 8.63±0.29(Predicted)
• Flash Point: 165 °F
• PSA: 45.82000
• Density: 0.97 g/mL at 25 °C(lit.)
• LogP: 2.14260

Purity/Quality:

99% ^*data from raw suppliers

6-NITRO-1-HEXENE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 6-NITRO-1-HEXENE, 97

There total 2 articles about 6-NITRO-1-HEXENE, 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

1-bromo-1-nitrohex-5-ene (133367-88-1) → 1-nitrohex-5-ene (4812-17-3) + 1-methyl-2-nitro-cyclopentane (102153-88-8)

Guidance literature:

2,2'-azobis(isobutyronitrile); In toluene; at 40 ℃; Mechanism; Irradiation;

Reference yield: 45.0%

6-Bromo-1-hexene (2695-47-8) → 1-nitrohex-5-ene (4812-17-3)

Guidance literature:

With sodium nitrite; In N,N-dimethyl-formamide; at 20 ℃; for 2h;

DOI:10.1021/ol070557k

Reference yield: 90.0%

1-nitrohex-5-ene (4812-17-3) → 1-nitrohexane (646-14-0)

Guidance literature:

With hydrogen; In methanol; at 20 ℃; for 7h; chemoselective reaction;

DOI:10.1016/j.tet.2012.07.044

upstream raw materials:

1-bromo-1-nitrohex-5-ene

6-Bromo-1-hexene

Downstream raw materials:

5-hexenoic acid

1-adamanthanol

1-bromo-4-[(1E)-6-nitrohex-1-enyl]benzene

1-nitrohexane

Refernces

• 1、 Marsh, Graham P.,Parsons, Philip J.,McCarthy, Clive,Cornique, Xavier G.. "An efficient synthesis of nitroalkenes by alkene cross metathesis: Facile access to small ring systems". . p. 2613 - 2616. Retrieved 2008/02/08.
• 2、 Andersen, Soeren H.,Das, Nalin B.,Joergensen, Ruth D.,Kjeldsen, Gunhild,Knudsen, Jes S.,et al.. "Silyl Nitronates in Organic Synthesis. Routes to Heterocycles and Cyclopentanoids. Synthesis of Allethrolone and Calythrone. Acylation and Cyanohydroxylation of Double Bonds. An Exploratory Study". . p. 1 - 14. Retrieved 2007/10/02.