(4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

Base Information

Chemical Name:(4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane
CAS No.:871809-99-3
Molecular Formula:C₂₉H₅₀O₄
Molecular Weight:462.714
Hs Code.:

Synonyms:(4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

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Chemical Property of (4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

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Technology Process of (4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

There total 6 articles about (4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 871809-97-1
(4S,6R)-4-[(R)-2-benzyloxy-4-(4-benzyloxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

: 871809-99-3
(4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; at 20 ℃; for 6h;
DOI:10.1016/j.tetlet.2005.09.146

Reference yield:

: 871809-93-7
(+)-(3R)-1-[4-(benzyloxy)phenyl]hex-5-en-3-ol

: 871809-99-3
(4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

Guidance literature:: Multi-step reaction with 5 steps

1: 85 mg / sodium hydride; tetra-n-butyl ammonium iodide / tetrahydrofuran / 20 °C

2: 75 percent / CuCl; O₂ / PdCl₂ / dimethylformamide; H₂O / 48 h / 20 °C

3: 470 mg / LiBH₄ / CH₂Cl₂ / 2 h / -78 °C

4: 72 percent / camphorsulfonic acid; molecular sieves 3 Angstroem / acetone / 20 °C

5: 70 percent / H₂ / palladium on carbon / ethyl acetate / 6 h / 20 °C / 760 Torr

With lithium borohydride; 3 A molecular sieve; camphor-10-sulfonic acid; hydrogen; oxygen; tetra-(n-butyl)ammonium iodide; sodium hydride; copper(l) chloride; palladium on activated charcoal; palladium dichloride; In tetrahydrofuran; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetone; 2: Wacker oxidation;
DOI:10.1016/j.tet.2006.07.076

Reference yield:

: 871809-94-8
(R)-4-benzyloxy-6-(4-benzyloxyphenyl)hex-1-ene

: 871809-99-3
(4S,6R)-4-[(R)-2-hydroxy-4-(4-hydroxyphenyl)butyl]-2,2-dimethyl-6-n-tridecyl-[1,3]dioxane

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / CuCl; O₂ / PdCl₂ / dimethylformamide; H₂O / 48 h / 20 °C

2: 470 mg / LiBH₄ / CH₂Cl₂ / 2 h / -78 °C

3: 72 percent / camphorsulfonic acid; molecular sieves 3 Angstroem / acetone / 20 °C

4: 70 percent / H₂ / palladium on carbon / ethyl acetate / 6 h / 20 °C / 760 Torr

With lithium borohydride; 3 A molecular sieve; camphor-10-sulfonic acid; hydrogen; oxygen; copper(l) chloride; palladium on activated charcoal; palladium dichloride; In dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; acetone; 1: Wacker oxidation;
DOI:10.1016/j.tet.2006.07.076