2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane

Base Information

• Chemical Name: 2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane
• CAS No.: 798568-62-4
• Molecular Formula: C₁₅H₂₈O₂Si
• Molecular Weight: 268.472
• Mol file: 798568-62-4.mol

Synonyms:2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane

Chemical Property of 2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane

Chemical Property:

Purity/Quality:

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Technology Process of 2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane

There total 1 articles about 2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene (31469-15-5) + (cyclohexylidenemethyl)(phenyl)iodonium tetrafluoroborate → 2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane (798568-62-4)

Guidance literature:

With triethylamine; In chloroform; at 20 ℃; for 2h;

DOI:10.1016/j.tetlet.2004.09.002

Reference yield: 98.0%

2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane (798568-62-4) → 1-chloro-1-cyclohexylidene-2-methoxy-3-methylbut-2-ene

Guidance literature:

With tin(IV) chloride; In dichloromethane; at -78 ℃; for 0.166667h;

DOI:10.1016/j.tetlet.2004.09.002

Reference yield: 95.0%

2-cyclohexylidene-1-methoxy-3,3-dimethyl-1-trimethylsilyloxycyclopropane (798568-62-4) → methyl 3-cyclohexylidene-2,2-dimethylpropanoate

Guidance literature:

With hydrogenchloride; In dichloromethane; at 0 ℃;

DOI:10.1016/j.tetlet.2004.09.002

upstream raw materials:

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene

Downstream raw materials:

2-cyclohexylidene-3,5,5-trimethyl-3-trimethylsilyloxycyclopentanone